Determination of diffusion coefficient of lithium in substituted LiMn1.95Cr0.05O4 spinel using impedance technique

Чуриков, А. В.; Romanova, V. O.

doi:10.1134/s1023193513030063

Cited by 4 publications

(2 citation statements)

References 24 publications

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“…(2) The impedance spectrum of commercial lithium-ion batteries is notoriously difficult to interpret. Churikov et al [3] studied the electrical diffusion properties of chromium-substituted lithium-manganese spinel Li x-Mn 1.95 Cr 0.05 O 4 used as cathode material for lithium-ion batteries and discussed the selection of equivalent circuits and the correct interpretation of equivalent circuit elements. (3) Hirose et al [4] emphasised the importance of choosing a suitable equivalent circuit to model the impedance response.…”

Section: Introductionmentioning

confidence: 99%

Comparative study of two equivalent circuit models for electrochemical impedance spectroscopy analysis of epoxy zinc-rich coatings

Xie,

Wang,

Xie

et al. 2023

Corrosion Engineering, Science and Technology: The Internationa

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In this paper, the impedance spectra of an epoxy zinc-rich coating (ZRC) and its free film immersed in 3.5% NaCl solution are investigated, the fitting error and model parameter trends of series and nested equivalent circuit fits are compared, and the differences in the high-frequency components of the ZRC and the epoxy coatings are analyzed. The results show that the high-frequency impedance of ZRC is the contact impedance between the zinc powders (Z m ) rather than the film impedance (Z f ). The corrosion reaction of the ZRCs is controlled by the diffusion of oxygen. For ZRCs, the series equivalent circuits are more reasonable compared to the nested equivalent circuit. Based on the series equivalent circuit, the variation law of the equivalent circuit elements (resistors, capacitors and dispersion coefficient) and the correlation of these elements with low-frequency impedance modulus (|Z| 0.01Hz ) and open circuit potential (OCP) are investigated in this paper.

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Section: Introductionmentioning

confidence: 99%

Comparative study of two equivalent circuit models for electrochemical impedance spectroscopy analysis of epoxy zinc-rich coatings

Xie,

Wang,

Xie

et al. 2023

Corrosion Engineering, Science and Technology: The Internationa

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“…R 3 is the charge-transfer resistance during the electrochemical reaction process. W 1 represents the Warburg impedance concerning the diffusion of Li + into the bulk electrode and C 1 and C 2 represent the constant phase elements that are used to cancel the measurement error and hysteresis effect [30,34].…”

Section: Electrochemical Impedance Spectroscopymentioning

confidence: 99%

High-performance of sodium carboxylate-derived materials for electrochemical energy storage

Zhu

Zhang

et al. 2018

Sci. China Mater.

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Diffusion aspects of lithium intercalation as applied to the development of electrode materials for lithium-ion batteries

Чуриков

Ivanishchev

Ushakov

et al. 2013

J Solid State Electrochem

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Determination of diffusion coefficient of lithium in substituted LiMn1.95Cr0.05O4 spinel using impedance technique

Cited by 4 publications

References 24 publications

Comparative study of two equivalent circuit models for electrochemical impedance spectroscopy analysis of epoxy zinc-rich coatings

Comparative study of two equivalent circuit models for electrochemical impedance spectroscopy analysis of epoxy zinc-rich coatings

High-performance of sodium carboxylate-derived materials for electrochemical energy storage

Diffusion aspects of lithium intercalation as applied to the development of electrode materials for lithium-ion batteries

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