Determination of dissolved hexavalent chromium in industrial wastewater effluents by ion chromatography and post-column derivatization with diphenylcarbazide

Arar, Elizabeth J.; Pfaff, John D.

doi:10.1016/s0021-9673(01)93031-6

Cited by 67 publications

(16 citation statements)

References 8 publications

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“…One of the most popular methods for the separation of the Cr(III)-Cr(VI) species is the extraction of Cr(VI) with a liquid anion exchange solution (Amberlite LA-2/MIBK; Camara et al, 2000). Ion chromatography is also used for the separation of Cr species successfully (Arar & Pfaff, 1991, Arar et al, 1992Giuriati et al, 2005) and is adopted by US-EPA in method 7199, which describes the determination of hexavalent chromium in drinking water, groundwater, and industrial wastewater effluents by ion chromatography (U. S. EPA, 1996b). Detection is mainly accomplished by spectrophotometry at 540 nm, utilizing the well-documented diphenylcarbazide method (Arar & Pfaff, 1991;Giuriati et al, 2005;Wei et al, 1982).…”

Section: Speciation Of Cr(vi) and Cr(iii)mentioning

confidence: 99%

“…Ion chromatography is also used for the separation of Cr species successfully (Arar & Pfaff, 1991, Arar et al, 1992Giuriati et al, 2005) and is adopted by US-EPA in method 7199, which describes the determination of hexavalent chromium in drinking water, groundwater, and industrial wastewater effluents by ion chromatography (U. S. EPA, 1996b). Detection is mainly accomplished by spectrophotometry at 540 nm, utilizing the well-documented diphenylcarbazide method (Arar & Pfaff, 1991;Giuriati et al, 2005;Wei et al, 1982). However, in order to achieve lower detection limits, ion chromatography has been coupled with atomic spectrometric detection systems, such as flame atomic absorption spectrometry (Posta et al, 1993) and inductively coupled plasma with atomic emission spectrometry (Byrdy et al, 1995), or mass spectrometry (Arar et al, 1992;Byrdy et al, 1995).…”

Section: Speciation Of Cr(vi) and Cr(iii)mentioning

confidence: 99%

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Fate and Biotransformation of Metal and Metalloid Species in Biological Wastewater Treatment Processes

Stasinakis

Thomaidis

2010

Critical Reviews in Environmental Science and Technology

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Suspended and attached growth wastewater treatment processes are widely used for the removal of biodegradable organic constituents and nutrients from wastewater. The frequent detection of toxic metals and metalloids in wastewater contributed to the publishing of numerous papers in the past, investigating their presence, toxicity and behavior in biological wastewater treatment systems (BWTS). In most of these studies, data were referred to total element concentration. However, nowadays it is generally accepted that toxicological and physicochemical properties are differentiated according to elemental speciation. The literature review revealed that there are enough studies investigating chromium species presence, toxicity, fate and biotransformation in BWTS, whereas there are fewer data for organotin compounds. Even less studies exist for arsenic, mercury and selenium species. Most of the results are referred to the activated sludge process. The biotransformation mechanisms are element-dependent. The reduction of Cr(VI) to Cr(III), the sequential debutylation of tributyltin and triphenyltin to inorganic tin, the oxidation of As(III) to As(V) and their methylation to organoarsenicals have been observed. Despite the gaps in the literature, these preliminary, in many cases, results indicate that biological wastewater treatment processes could be used in the future for the detoxification of metal-and metalloid-laden wastewater, allowing the reuse of wastewater and sludge.

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Section: Speciation Of Cr(vi) and Cr(iii)mentioning

confidence: 99%

Section: Speciation Of Cr(vi) and Cr(iii)mentioning

confidence: 99%

Fate and Biotransformation of Metal and Metalloid Species in Biological Wastewater Treatment Processes

Stasinakis

Thomaidis

2010

Critical Reviews in Environmental Science and Technology

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“…HPLC with a convenient detector meets most of the analytical requirements of simultaneous metal determination such as separation, identification, and quantification of different species down to trace levels. A significantly higher sensitivity is achieved by using derivative HPLC with spectrophotometric detection (Arar and Pfaff 1991;Pobozy et al 1996;Padarauskas and Schwedt 1995). Derivative HPLC is not only a sensitive but also a selective and rapid method for the separation and determination of metal ions.…”

Section: Introductionmentioning

confidence: 99%

Determination of cobalt, nickel and iron at trace level in natural water samples by in-column chelation-reversed phase high-performance liquid chromatography

Höl

Divrikli

Elçi

2011

Environ Monit Assess

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This paper reports the utilization of 4-(2-pyridylazo) resorcinol (PAR) as a chelating reagent for in-column derivatization and the determination of trace Co, Fe, and Ni ions by reversed-phase high-performance liquid chromatography with photodiode array detector. A good separation of Co, Fe, and Ni chelates were achieved by using an Inertsil ODS-3 column and a mobile phase, consisted of methanol-THF-water mixture (50:5:45) containing ammonium acetate buffer (pH 5.0) and PAR. After full optimization, good repeatability of retention times (relative standard deviation (RSD) < 0.05%) and peak areas (RSD < 1.7%) was achieved as well as a good linearity (r (2) > 0.9991). The detection limits (S/N = 3), expressed as micrograms per liter, were 0.50 (Co), 9.07 (Fe), and 2.00 (Ni). The applicability and the accuracy of the developed method were estimated by the analysis of spiked water samples and certified reference material BCR 715 wastewater-SRM.

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“…The commonly used methods for chromium determination include the spectrophotometric [5][6][7], chromatographic [8,9], flow injection-fluorimetric [10][11][12], atomic absorption [13][14][15][16] and electrochemical methods such as voltammetry [17][18][19] and polarography [20][21][22].…”

Section: Introductionmentioning

confidence: 99%

“…A method for determination of microquantities of Cr(VI) in soils and alloys is suggested [5]. Chromium in drinking water, groundwater and industrial wastewater effluents could be determined using ion chromatographic techniques [9].…”

Section: Introductionmentioning

confidence: 99%

Investigation of polarographic interference between Se(IV) and Cr(VI), its elimination and application to Gerede river water

Yilmaz

Somer

2009

Journal of Electroanalytical Chemistry

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Determination of dissolved hexavalent chromium in industrial wastewater effluents by ion chromatography and post-column derivatization with diphenylcarbazide

Cited by 67 publications

References 8 publications

Fate and Biotransformation of Metal and Metalloid Species in Biological Wastewater Treatment Processes

Fate and Biotransformation of Metal and Metalloid Species in Biological Wastewater Treatment Processes

Determination of cobalt, nickel and iron at trace level in natural water samples by in-column chelation-reversed phase high-performance liquid chromatography

Investigation of polarographic interference between Se(IV) and Cr(VI), its elimination and application to Gerede river water

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