Determination of indium, chromium, and iron in double alkali phosphate compounds

Ivanenko, A. P.; Nagornyi, P. G.; Kornienko, Z. I.; Boiko, R. S.; Zatovskii, I. V.

doi:10.1134/s106193480712012x

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2012

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“…Phosphorus was determined as described in [5]; indium, chromium, and iron, by a rapid method as described in [6]; and manganese as described in [7]. X ray diffraction patterns were recorded for com pounds and solid solutions on a DRON 3.0 diffracto meter (CuK α radiation; 2 deg/min).…”

Section: Methodsmentioning

confidence: 99%

Synthesis of substitutional solid solutions in Na2O-P2O5-In2O3-M 2 III O3 (MIII = Cr, Fe, and Mn) systems

Ivanenko

Nagorny

Boiko

et al. 2012

Russ. J. Inorg. Chem.

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Solid solutions based on Na 7 (InP 2 O 7 ) 4 PO 4 and Na 3 In 2 (PO 4 ) 3 , where chromium, iron, and man ganese substitute for indium, have been prepared. When chromium and iron substitute for indium in Na 7 (InP 2 O 7 ) 4 PO 4 , a continuous solid solution series exists. When manganese substitutes for indium, it enters the compound in the oxidation state +3. The substitution of chromium for indium in Na 3 In 2 (PO 4 ) 3 occurs within the range from 0.11 to 0.74 (mol/mol), and that of iron for indium, from 0.09 to 0.62 (mol/mol). When manganese substitutes for indium, it enters the structure of the crystalline phase in insignificant amounts as a two charged cation.

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Section: Methodsmentioning

confidence: 99%