Determination of metrafenone in bitter gourd and soil by GC with ECD

Wang, Siwei; Yan-ping, Liu; Sun, Haibin

doi:10.1016/j.foodchem.2015.09.019

Cited by 3 publications

(1 citation statement)

References 13 publications

(8 reference statements)

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“…[10] Biaryl ketones are highly valued as versatile synthetic intermediates and crucial building blocks in various fields including synthetic chemistry, pharmaceutical chemistry, agrochemicals, and frag-ment-based drug discovery (FBDD). They find widespread applications, such as in important herbicides I, [11] systemic fungicides II, [12] electrical material precursors III, [13] inhibitor agents IV, [14] and Leismanidal Lead V [15] (Scheme 2a). Traditionally, biaryl ketones are synthesized through the Friedel-Crafts acylation of aryl halides or acid anhydrides, typically requiring large quantities of Lewis acids.…”

Section: Applications Of Catalystmentioning

confidence: 99%

Carbonylative Self‐Coupling of Aryl Boronic Acids Using a Confined Pd Catalyst within Melamine Dendron and Fibrous Nano‐Silica: A CO Surrogate Approach

Kolekar

Saptal

Bhanage

2023

Chemistry A European J

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Development of heterogeneous catalysts with tunable activity and selectivity has posed a persistent challenge. This study addresses this challenge by fabricating a hybrid environment through the combination of mesoporous silica and N-rich melamine dendron via covalent grafting, allowing for control-lable growth and encapsulation of Pd NPs. This catalyst presented an excellent catalytic activity for the oxidative carbonylative self-coupling of aryl boronic acids to afford symmetric biaryl ketones using N-formyl saccharin as a sustainable solid CO source and Cu as a co-catalyst.

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