2007
DOI: 10.1039/b708018b
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Determination of natural Sr and 90Sr in environmental samples by ETV-ICP-MS

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Cited by 27 publications
(16 citation statements)
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“…Comparison of two ETV devices, a commercial graphite tube unit and an in-house W-coil, for determination of 90 Sr in environmental samples by ETV-ICP-MS demonstrated that interferences from 90 Y and 90 Zr were removed when these elements were present at concentrations up to 1 and 100 mg kg -1 , respectively, an improvement of 15 and 30-fold over solution nebulisation (Grinberg et al 2007). However, accurate results still required additional interference removal via the reaction cell present in the ICP-MS instrument.…”
Section: Electrothermal Vaporisationmentioning
confidence: 99%
“…Comparison of two ETV devices, a commercial graphite tube unit and an in-house W-coil, for determination of 90 Sr in environmental samples by ETV-ICP-MS demonstrated that interferences from 90 Y and 90 Zr were removed when these elements were present at concentrations up to 1 and 100 mg kg -1 , respectively, an improvement of 15 and 30-fold over solution nebulisation (Grinberg et al 2007). However, accurate results still required additional interference removal via the reaction cell present in the ICP-MS instrument.…”
Section: Electrothermal Vaporisationmentioning
confidence: 99%
“…Determination of low level of 90 Sr by ICP-MS is also challenging due to the high specific activity of 90 Sr and the presence of isobaric interferences (e.g., 90 Y, 90 Zr) originating from the sample matrix and 90 Sr decay. These issues remain to be properly addressed via enhancement in instrumental sensitivity and adequate separation before mass spectrometric measurement of this radionuclide can become routine [10,11].…”
Section: Introductionmentioning
confidence: 99%
“…Up to now, several mass spectrometric techniques have been applied for 90 Sr analyses including accelerator mass spectrometry (AMS) (Paul et al, 1997;Arslan et al, 1994), resonance ionisation mass spectrometry (RIMS) (Bushaw and Cannon, 1997;Bushaw and Nö rtershä user, 2000;Monz et al, 1993;Zimmer et al, 1994), inductively coupled plasma mass spectrometry (ICP-MS) and electrothermal vaporization-ICP-MS (ETV-ICP-MS) (Berryman and Probst, 1996;Grinberg et al, 2007). AMS and particularly RIMS allow high isotopic and elemental selectivity and thus are suitable for determination of 90 Sr with detection limits down to 2 mBq per sample .…”
Section: Introductionmentioning
confidence: 99%
“…Abundance sensitivity was reported to be less than 10 À10 which is competitive with AMS and RIMS. Grinberg et al (2007) used a combination of ETV-ICP-MS and DRC technology and obtained procedural detection limits from 2 to 20 pg g À1 for 90 Sr depending on the concentrations of Zr and Y in samples.…”
Section: Introductionmentioning
confidence: 99%