1975
DOI: 10.1063/1.431640
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Determination of solute properties by solvent vapor pressure measurements. II. Simple electrolytes, polyelectrolytes, and complex ions

Abstract: A recently developed empirical method for the determination of solute parameters by solvent vapor pressure measurements is further explained and demonstrated. The results of our laboratory and those of two other laboratories have shown that the osmotic coefficient of water is practically constant over the range 0.02–0.1m. This is consistent with the above-mentioned method. Examples are given for solutions of simple electrolytes, polyelectrolytes, and complex ions.

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Cited by 1 publication
(2 citation statements)
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“…4− ions 27 and hydrogel framework (Figure S3) on the saturated vapor pressure is negligible. Within the hydrogel, the concentration of Li + and Br − ions in the sample was 5.4 M, which corresponds to a saturated vapor pressure of 2.22 kPa.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
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“…4− ions 27 and hydrogel framework (Figure S3) on the saturated vapor pressure is negligible. Within the hydrogel, the concentration of Li + and Br − ions in the sample was 5.4 M, which corresponds to a saturated vapor pressure of 2.22 kPa.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…The explanation for the structural stability is the presence of Li + and Br – , which decrease the saturated vapor pressure of water inside the hydrogel. The effect of Fe­(CN) 6 3– and Fe­(CN) 6 4– ions and hydrogel framework (Figure S3) on the saturated vapor pressure is negligible. Within the hydrogel, the concentration of Li + and Br – ions in the sample was 5.4 M, which corresponds to a saturated vapor pressure of 2.22 kPa .…”
Section: Resultsmentioning
confidence: 99%