Determination of standard gibbs energies of formation of Fe2Mo3O12, Fe2Mo3O8, Fe2MoO4, and FeMoO4 of the Fe-Mo-O ternary system and μ phase of the Fe-Mo binary system by electromotive force measurement using a Y2O3-stabilized ZrO2 solid electrolyte

Thermal expansion anisotropy of Fe23Mo16 and Fe7Mo6 μ-phases predicted using first-principles calculations

“…[14][15][16][17] Precipitations of the m-phase in nickel-based alloys were studied by scanning, transmission electron microscopy, and X-ray diffraction by Zhao et al 18 A study of the m-phases precipitated in superalloys at T = 800 1C, where the thermal treatment reached 10 000 hours, was performed by Qin et al 19 Studies of the distribution of atoms over different sublattices, the structure and lattice parameters of m-phases were carried out. 20,21 The phase diagrams of Co-Mo and Fe-Mo systems by means of a combination of ab initio electronic structure calculations and the CALPHAD approach were obtained by Houserova ´et al 22 The formation of standard Gibbs energies for compounds of the Fe-Mo-O system was experimentally obtained by Koyama et al 23 Thus, most of these works are focused on the structural properties of m-phases. But the thermodynamic and elastic properties of Fe 23 Mo 16 and Fe 7 Mo 6 are not compared.…”

First‐Principles Calculations of the Thermal Expansion Path of the Co7Mo6 μ‐Phase

“…The phase diagrams of Co-Mo and Fe-Mo systems by means of a combination of ab initio electronic structure calculations and the CALPHAD approach were calculated by Houserová et al [22]. The formation of standard Gibbs energies for compounds of the Fe-Mo-O system was experimentally obtained by Koyama et al [23].…”