Determination of the relative oxidative stability of petroleum bitumens by thermogravimetry

Herrington, P R; Ball, G.F.A.; Patrick, John

doi:10.1016/0040-6031(92)85164-q

Cited by 7 publications

(2 citation statements)

References 13 publications

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“…1 shows an example with bitumen duplicates. Due to poor reproducibility, the DTGA profile has not permitted successful fingerprinting of bitumen [7]. Alternative methods used to overcome this difficulty have consisted of the measurement of weight loss at fixed temperatures, e.g.…”

Section: Introductionmentioning

confidence: 99%

Solventless fingerprinting of bituminous materials: A high-resolution thermogravimetric method

Masson

Bundalo-Perc

2005

Thermochimica Acta

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/npsi/ctrl?lang=en http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/ctrl?lang=fr Access and use of this website and the material on it are subject to the Terms and Conditions set forth at http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/jsp/nparc_cp.jsp?lang=en NRC Publications Archive Archives des publications du CNRCThis publication could be one of several versions: author's original, accepted manuscript or the publisher's version. / La version de cette publication peut être l'une des suivantes : la version prépublication de l'auteur, la version acceptée du manuscrit ou la version de l'éditeur. Thermochimica Acta, 436, 1-2, pp. 35-42, 2005-10-01 Solventless fingerprinting of bituminous materials: a high-resolution thermogravimetric method Masson, J-F.; Bundalo-Perc, S. AbstractThe thermogravimetric analysis (TGA) of bituminous materials by means of a constant heat rate is often plagued by low resolution and poor reproducibility of the degradation or mass loss temperatures. The TGA curve, or the associated differential TGA (DTGA) signal, is thus an unreliable quality control or quality assurance (QC/QA) method. A 2-and 3-step high-resolution TGA/DTGA method was developed for these materials for analysis between 150°C and 800°C. The DTGA results, obtained within 2h, show about ten discrete mass peaks, the profile being material dependant. The reproducibility of the results indicate that the methods may be used for rapid QC/QA and material fingerprinting. The development of the method is detailed and its application is illustrated with the analysis of several bitumens and polymer-modified bituminous sealants.

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Section: Introductionmentioning

confidence: 99%

Solventless fingerprinting of bituminous materials: A high-resolution thermogravimetric method

Masson

Bundalo-Perc

2005

Thermochimica Acta

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“…Karacan and Kok [8] showed that major SARA (saturates, aromatics, resin, and asphaltene) fractions of crude oil are thermally degraded via independent reactions and also that TGA is useful to calculate kinetic parameters such as the activation energy to characterize their thermal degradation [9][10]. Thus, TGA has been used to assess relative oxidative stabilities for a number of bitumens and exposed a correlation between activation energy and lifetime in the field [11].…”

Section: Introductionmentioning

confidence: 99%

Thermogravimetric monitoring of oil refinery sludge

Barneto

Moltó

Ariza

et al. 2014

Journal of Analytical and Applied Pyrolysis

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The present work has two dimensions: analytical and environmental. On the one hand we proved that thermogravimetric analysis can be used to perform fast characterization of oil refinery sludge. To this end, thermogravimetric curves were deconvoluted by using autocatalytic kinetics to take into account acceleratory phases in a thermal degradation performed in oxygen-containing atmosphere or at high heating rates. Based on thermogravimetric results, oil refinery sludge was modeled in terms of various fractions (pseudo-components) which degrade as major oil cuts. On the other hand, as an alternative to landfill, we have seen that Soxhlet extraction allows recovery almost half of the weight of sludge as a mixture of hydrocarbons, similar to gas-oil, which burns without residue. This ensures both, waste inerting and significant reduction in sludge volume.

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Kinetic study of the effect of in-situ mineral solids on pyrolysis process of oil sludge

Wang

et al. 2019

Chemical Engineering Journal

112

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Determination of the relative oxidative stability of petroleum bitumens by thermogravimetry

Cited by 7 publications

References 13 publications

Solventless fingerprinting of bituminous materials: A high-resolution thermogravimetric method

Solventless fingerprinting of bituminous materials: A high-resolution thermogravimetric method

Thermogravimetric monitoring of oil refinery sludge

Kinetic study of the effect of in-situ mineral solids on pyrolysis process of oil sludge

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