The activity concentrations of some radionuclides ( 238 U, 234 U, 230 Th, 226 Ra, 232 Th, 40 K and 235 U) were measured by γ-ray spectrometry in order to study their behavior and the relation between them in Carboniferous rock samples collected from Gabal (mountain) Um-Hamd, southwestern Sinai, Egypt. The whole samples are located in the two limbs and trough of a synclinal form structure to identify the radionuclides migration processes which have occurred in these rock samples. The average activity concentrations of 238 U