Using a Penning trap single ion mass spectrometer, we have measured the atomic masses of 13 isotopes, many important for fundamental metrology and fundamental constants. The accuracy of the measurements, w 10~~1 0 , is typically two orders of magnitude better than previously accepted values. A wide variety of self consistency checks greatly reduces the possibility of unknown systematic errors. As part of a program to determine the Molar Planck constant N^h and the fine structure constant a, we measured the masses of 133 Cs, 87)85 Rb, and 23 Na. Our high accuracy atomic mass measurements can be combined with values of h/m atom from atom interferometry measurements and accurate wavelength measurements for different atoms to give several independent determinations of N^h and a. This route to a through N^h, the atomic mass of the proton M p , the electron to proton mass ratio m e /m p , and the Rydberg constant R<^ is based on simple physics. It can potentially achieve the several ppb accuracy needed to test the QED determination of a extracted from measurements of the electron g factor.