Determining the constant diffusion coefficient by Fourier series solution of the diffusion equation

Abstract

The purpose of this study was to obtain the diffusion coefficient by calculating directly from the Fourier series solution of the diffusion equation, which has not been studied so far. The Fourier series solution is the sum of a steady-state solution and a transient solution. The steady-state solution is a linear function of distance. The transient solution is the product of a distance function and a time function. The Fourier sine series solution, a function of distance only, is negative for the steady-state solution. For the sublimation diffusion of disperse dye in paste into polyethylene terephthalate (PET) film using the film-roll method, the constant surface concentration and the diffusion distance were determined from the quadratic regression curve for the concentration distribution at a long time. The concentration distribution of the transient solution is a downwardly convex curve with negative values. The concentration distribution of the Fourier series solution is also a downwardly convex curve. The diffusion coefficient in the exponential term, a function of time only, was determined from the value of the exponential term obtained by the surface concentration and the diffusion distance. The constant diffusion coefficients determined from the Fourier series solution are reliable because they are very similar to those obtained from the error function solution and have excellent linearity of the linear regression lines for their Arrhenius plots.