This work presents a numerical study of detonation initiation by means of a focusing shock wave. The investigated geometry is a part of a pulsed detonation combustion chamber, consisting of a circular pipe in which the flow is obstructed by a single convergent–divergent axisymmetric nozzle. This obstacle acts as a focusing device for an incoming shock wave, serving as a low-energy detonation initiator. The chamber is filled with stoichiometric premixed hydrogen-enriched air. The simulation uses a one-step chemical model with variable parameters optimized by the adjoint approach in terms of the induction time $$\tau _{\text {c}}$$
τ
c
. The model reproduces $$\tau _{\text {c}}$$
τ
c
of a complex kinetics model in the range of pressures and temperatures appearing at the focusing point. The results give a comprehensive description of the shock-induced detonation initiation, which is the mechanism for the deflagration-to-detonation transition in this type of configurations. Potential geometry design improvements for technical applications are discussed. The first attempt to parameterize the transition process is also undertaken.