2002
DOI: 10.1016/s0925-9635(01)00723-3
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Detonation synthesis ultradispersed diamond structural properties investigation by infrared absorption

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Cited by 90 publications
(37 citation statements)
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“…The ζ -potential of an ultra-fine particle is often used to evaluate the variety and intensity of charge, and it is a very important index that reflects the repulsive force intensity among particles and the dispersion stability. There exist such functional groups as -COOH, -OH, -NH 2 , and the like on the surface of nanodiamond [6]. The kinds and intensity of functional groups affect its sorption behavior and ionization properties.…”
Section: Introductionmentioning
confidence: 99%
“…The ζ -potential of an ultra-fine particle is often used to evaluate the variety and intensity of charge, and it is a very important index that reflects the repulsive force intensity among particles and the dispersion stability. There exist such functional groups as -COOH, -OH, -NH 2 , and the like on the surface of nanodiamond [6]. The kinds and intensity of functional groups affect its sorption behavior and ionization properties.…”
Section: Introductionmentioning
confidence: 99%
“…It is unlikely that the non-diamond (sp 2 ) carbon is exclusively responsible for these features of the Raman spectra. Additional molecular groups and fragments can also be formed in DCM particles under rapid quenching followed by condensation, as shown in previously published IR spectra of DCM [8][9][10][11]. According to [5], the broad asymmetric Raman band between 1500 and 1700 cm −1 originates from O-H bending vibrations and C=O stretching vibrations.…”
Section: Resultsmentioning
confidence: 65%
“…Ester groups, which constitute structural units of heterogeneous DCM particles, also complicate the spectra. Their concentration depends on the type of the DCM sample [8][9][10][11].…”
Section: Resultsmentioning
confidence: 99%
“…2) were characterized by the presence of the main absorption bands near 3600-3000 and 1620 cm -1 (OH groups), 3000-2800 cm -1 (CH x ), 1800-1700 cm -1 (CO), and 1400-700 cm -1 (N, CN, CO, CH groups, etc.). These bands are typical of the surface functional groups of UDD of other types [4,[19][20][21]. The main differences between the spectra of CH-7 and K-2 were the difference in the intensity of the 3000-2800 cm -1 band, the shape of the complex band at 1400-700 cm -1 , and the position and intensity of the 1800-1700 cm -1 band characterizing the configuration of surface C-O bonds (ketone groups, carboxyl anhydrides, and lactones [23]).…”
Section: Ir Spectroscopymentioning
confidence: 92%
“…The main reason for this is the substantial influence of the "hard" chemical procedure used to extract MND from meteorites on the chemistry of the surface of particles [14][15][16][17]. A similar dependence of the composition of the functional coating on the surface of nanodiamonds on the procedure for their technological purification is also characteristic of synthetic UDD [18][19][20][21]. With meteorite diamonds, the situation is aggravated by the use of different extraction procedures in different research centers.…”
Section: Introductionmentioning
confidence: 99%