Under the current ‘double carbon’ policy, the building materials manufacturing industry has seriously restricted the improvement of social and environmental benefits. Digital green innovation (DGI) in photovoltaic building materials enterprises (PBMES) plays a crucial role in solving the problems of high-quality environmental and economic development. In order to make the DGI of PBMES more effective, it is very critical to evaluate the performance of the DGI activities of PBMES. First, the evaluation index system is constructed. Then, it constructs the theoretical framework of the DGI performance evaluation of PBMES. After that, on the basis of combining various evaluation methods, a combination evaluation model based on compatibility and consistency was constructed and the convergence test and consistency test of the combination evaluation results were carried out by means of the variance method and Spearman rank correlation coefficient, which verified the scientificity and validity of the method. Finally, using the evaluation model, 16 PBMES were empirically studied. It reflected that the DGI performance evaluation index system of PBMES is composed of four indexes, namely, technology input, economic output, scientific and technological output, and social effect. The key factors affecting the DGI performance of PBMES are the investment in talent training, the proportion of digital technology in green products, the success rate of digital innovation product development increased by DGI cooperation, and the digital level of adopting environmental management system. This article combines consistency-based evaluation methods to not only obtain reasonable evaluation results, but also fully utilize multi-level methods to better describe the evaluation object. The means provided in this article are a new way to solve the DGI performance evaluation of PBMES.