The
ABO3−δ-type perovskite oxides are highly
desirable electrocatalysts with interesting surface structures that
could be modified to bring out their excellent catalytic performance.
The La0.6Sr0.4CoO3−δ (LSC) perovskite is one among the classes which is easy to fabricate,
cost-effective, and scalable. Defect engineering by sintering and
interface engineering by in situ surface modification are employed
to positively transform the LSC perovskite electrode, that is, by
sintering at a high temperature, phase-pure LSC is obtained with induced
changes such as improved conductivity, crystal defects, and oxygen
vacancies. By chemically modifying the surface of this LSC using highly
catalytically active NiFe layered double hydroxide (LDH), excellent
bifunctionality is achieved. For the latter, an optimized molar ratio
of NiFe LDH (25%) is integrated onto the phase-pure LSC surface by
a simple wet-chemical process. The phase purity and bifunctionality
of the prepared composite are verified by various physical characterizations
and redox processes. The surface-modified LSC/LDH (75/25) cathode
demonstrates superior oxygen reduction and evolution reaction performances
that are better than those of the native LSC with a low overall overpotential
of 0.71 V at 5 mA cm–2 in alkaline media. The same
cathode when applied in a zinc–air battery exhibits a stable
cycle performance with a reduced charge–discharge potential
gap of 0.73 V at 5 mA cm–2 for 100 cycles in alkaline
media. Additionally, LSC/LDH (75/25) also ensures long-term performance
with remarkable stability.