Progress in microwave and millimeter-wave technologies has enabled advanced diagnostics for industrial applications. The transmission, reflection, scattering and radiation processes of electromagnetic waves are utilized as diagnostic principles. Specifically, the reflectometric method has gained importance in various applications due to the possibility of the high localization and accessibility of measurements, as well as the non-destructive nature of the systems. In this paper, radar reflectometers were applied to the measurement of the inside of a building wall, that is, the inspection of tile materials attached to a concrete wall. The measurement principle utilizes the phase interference effect of the reflected wave due to the multiple reflections between the two layers (Fabry–Perot effect). The results show the imaging inside the surface related to the peering condition between the tile and concrete wall, and the quantitative evaluation of the condition with non-destructive inspection.