Development and progress of functionalized silica-based adsorbents for CO2 capture

Fatima, Syeda Saba; Borhan, Azry; Ayoub, Muhammad; Ghani, Noraini Abd

doi:10.1016/j.molliq.2021.116913

Cited by 40 publications

(17 citation statements)

References 191 publications

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“…Based on table 1, it is shown there are numerous studies of PEI supported to various types of adsorbents. Mainly from the mesoporous silica based due to its properties that are easy to be introduced to functional support [13]. From the data, it clearly showed the presence of impregnated PEI improves the adsorption capacity for all different types of adsorbents.…”

Section: Pei Impregnated Adsorbents For Co2 Capturementioning

confidence: 96%

“…PEI is one of the amine groups that have been widely used due to its high amino contain and good thermal stability [11]. Due to its beneficial behaviors, there are huge numbers of studies have reported on the use of PEI to enhance the CO2 uptake of various solid adsorbents such as silica [12,13], graphene oxide [14], metal oxide [15], metal-organic framework [16,17], etc.…”

Section: Introductionmentioning

confidence: 99%

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Amine (Polyethyleneimine)-modified solid adsorbent for CO₂ capture

Rani

Hitam

Taib

2022

J. Phys.: Conf. Ser.

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The increase in the concentration of carbon dioxide (CO2) gas in the atmosphere has led to various severe negative consequences. There are numerous methods for the reduction of CO2 that have been introduced such as chemical and physical absorption, organic liquid scrubbing, amine-based absorption, etc. Adsorption by using solid adsorbents is one of the promising methods that has been widely studied by researchers. The performance of the adsorbents can be enhanced by functionalized with diverse types of promoters. This review is discussing the performance of polyethyleneimine (PEI) as a promoter towards the adsorption of CO2. To achieve high effective PEI-adsorbents, the percentage of PEI amine loading, type of porous support, temperature, and different flow conditions are among the important parameters that need to be considered. The chemical stability of PEI can be improved through modification crosslinking of PEI. Hence in this review, the effect of amine loading, porous support, temperature, slow condition and crosslinking of PEI to its CO2 adsorption performance is observed.

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Section: Pei Impregnated Adsorbents For Co2 Capturementioning

confidence: 96%

Section: Introductionmentioning

confidence: 99%

Amine (Polyethyleneimine)-modified solid adsorbent for CO₂ capture

Rani

Hitam

Taib

2022

J. Phys.: Conf. Ser.

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“…Moreover, solid sorbents can be used for a wide temperature range from 25 to 700 °C, yielding less waste during cycling, and the used solid sorbents can be disposed without unnecessary environmental protections. Several solid sorbent materials with a porous texure have been used, such as porous coordination polymers (PCPs), 46 covalent organic frameworks (COFs), 47 metal−organic frameworks (MOFs), 48 zeolitic imidazolate frameworks (ZIFs), 49 zeolites, 50 silica-based materials, 51 boron nitride, 52 clay-based sorbents, 53 and metal oxides 54 and they show the excellent CO 2 capture efficiency. The advantage and disadvantage of using several solid sorbents have been tabulated in Table 6.…”

Section: Types Of Co 2 Capture Techniquesmentioning

confidence: 99%

Critical Review on Carbon-Based Nanomaterial for Carbon Capture: Technical Challenges, Opportunities, and Future Perspectives

Ramar¹,

Ambedkar²

2022

Energy Fuels

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In the 21st century, climate change and global warming are considered to be one of the world’s most severe and biggest environmental threats to humans. Consequently, the CO2 capture and storage technique has been a concern as a superior technique by both industrial and academic research communities, which prohibits the mixing of CO2 from point sources, such as cement plants and fossil fuel power plants, into the atmosphere. Particularly, after the United Nations Climate Change Conference in 2015, which was held in Paris, France, researchers have been vigorously focusing on the reduction of greenhouse gases. Presently, liquid amine scrubbing has been used for CO2 capture technology, while solid sorbents are used for CO2 capture technology to overcome the drawbacks associated with amine scrubbing technology. In this review, different carbon nanomaterials, such as fullerene, carbon nanotubes, graphene oxide, biochar, and activated carbon, and their derivatives for CO2 capture applications are summarized. In addition, the review covers the fundamental requirements of solid sorbents, advantages and disadvantages of other solid sorbents, and policies proposed for reducing greenhouse gas emissions by developing and developed countries, which will be highly beneficial for making future policies and fabricating low-cost CO2 sorbents. Finally, the current technical challenges and opportunities for the development of efficient and practically possible carbon-based CO2 sorbents were discussed. Furthermore, future perspectives were proposed for the development of carbonaceous porous materials in place of existing liquid amine scrubbing technology in the future.

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“…The CO 2 concentrations and pressures are higher for CO 2 separation from natural gas [15]. Generally, the following methods have been used for carbon dioxide capture from gases: absorption, adsorption, membrane separation, cryogenic distillation, hydrate-based CO 2 capture, chemical-looping combustion and biological separation using bacteria or algae [11,16]. Among these methods, absorption, adsorption and membrane separation are regarded as the most established and mature.…”

Section: Introductionmentioning

confidence: 99%

Comparison of CO2 Separation Efficiency from Flue Gases Based on Commonly Used Methods and Materials

Ziobrowski

Rotkegel

2022

Materials

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The comparison study of CO2 removal efficiency from flue gases at low pressures and temperatures is presented, based on commonly used methods and materials. Our own experimental results were compared and analyzed for different methods of CO2 removal from flue gases: absorption in a packed column, adsorption in a packed column and membrane separation on polymeric and ceramic membranes, as well as on the developed supported ionic liquid membranes (SILMs). The efficiency and competitiveness comparison of the investigated methods showed that SILMs obtained by coating of the polydimethylsiloxane (PDMS) membrane with 1-ethyl-3-methylimidazolium acetate ([Emim][Ac]) exhibit a high ideal CO2/N2 selectivity of 152, permeability of 2400 barrer and long term stability. Inexpensive and selective SILMs were prepared applying commercial membranes. Under similar experimental conditions, the absorption in aqueous Monoethanolamine (MEA) solutions is much faster than in ionic liquids (ILs), but gas and liquid flow rates in packed column sprayed with IL are limited due to the much higher viscosity and lower diffusion coefficient of IL. For CO2 adsorption on activated carbons impregnated with amine or IL, only a small improvement in the adsorption properties was achieved. The experimental research was compared with the literature data to find a feasible solution based on commercially available methods and materials.

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Development and progress of functionalized silica-based adsorbents for CO2 capture

Cited by 40 publications

References 191 publications

Amine (Polyethyleneimine)-modified solid adsorbent for CO₂ capture

Amine (Polyethyleneimine)-modified solid adsorbent for CO₂ capture

Critical Review on Carbon-Based Nanomaterial for Carbon Capture: Technical Challenges, Opportunities, and Future Perspectives

Comparison of CO2 Separation Efficiency from Flue Gases Based on Commonly Used Methods and Materials

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Development and progress of functionalized silica-based adsorbents for CO2 capture

Cited by 40 publications

References 191 publications

Amine (Polyethyleneimine)-modified solid adsorbent for CO2 capture

Amine (Polyethyleneimine)-modified solid adsorbent for CO2 capture

Critical Review on Carbon-Based Nanomaterial for Carbon Capture: Technical Challenges, Opportunities, and Future Perspectives

Comparison of CO2 Separation Efficiency from Flue Gases Based on Commonly Used Methods and Materials

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Product

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About

Amine (Polyethyleneimine)-modified solid adsorbent for CO₂ capture

Amine (Polyethyleneimine)-modified solid adsorbent for CO₂ capture