Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders

Abstract

The paper discusses various ways of activating phosphorus slags by introducing additives for the development of phosphorus slag binders (PSB), replacing cement. Considering that pseudowollastonite is the main mineral of phosphorus slags and without activating components does not possess the binding properties necessary for the production of building materials based on them, we used compositions of small amounts of sodium hydroxide with alkali metal salts, the anions of which form poorly soluble compounds with calcium. When choosing activating components, scarce alkaline additives were replaced by waste from chemical plants, which allows a passing solution of their practical use and environmental problems. The strength at a sodium hydroxide content of 1–4 % after curing of slag samples of various batches was in the range of 50.0–70.0 MPa. Samples of binders of normal hardening at the age of 28 days with a sodium hydroxide content of 0.5; 1.0, 2 and 4 % had the strength of 20.3; 35.4; 45.6; 55.8 MPa, respectively. The effect of the combined presence of alkali and salt is especially noticeable for small amounts of sodium hydroxide. Binders containing a composition of cement with salts under normal conditions and after curing showed a slightly lower strength than in an alkaline medium. With a constant cement content (4 %), the strength indicators increase with an increase in the proportion of the salt additive, reaching at 4 % its maximum value. The effect of the nature of activators on pH was determined. The data obtained indicate the advantages of using PSB and various industrial wastes with a low content of alkaline compounds in the production

Investigation of the Pozzolanic Activity Improvement of Yellow Phosphorus Slag with Thermal Activation

“…CaO and SiO 2 are the main components of YPS, and the glassy-phase content can reach 85-90% in YPS [14]. Therefore, YPS has potential pozzolanic activity and can be applied to the field of building materials such as cement, concrete, supplementary cementitious materials, road base materials and backfill materials [15,16]. A small amount of YPS replacing silicate cement in concrete can decrease the dosage of silicate cement.…”