Development of a chemiluminescence detection system using bis[4‐nitro‐2‐(3,6,9‐trioxadecyloxycarbonyl)phenyl] oxalate for the sensitive determination of the fluorescent compounds separated with an acidic mobile phase

Sugiura, Masaki; Kanda, Susumu; Imai, Kazuhiro

doi:10.1002/bmc.1130070310

Cited by 19 publications

(2 citation statements)

References 27 publications

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“…A continuous-flow system for chemiluminescence and bioluminescence assays has also been described (05). luminescence detection of fluorescent compounds separated in an acidic mobile phase (06). A two-dimensional CCD camera has been used for imaging fluorescent and chemiluminescent DNA hybrids (07).…”

Section: O Chemiluminescencementioning

confidence: 99%

Molecular Fluorescence, Phosphorescence, and Chemiluminescence Spectrometry

Soper¹,

McGown²,

Warner³

1994

Anal. Chem.

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Section: O Chemiluminescencementioning

confidence: 99%

Molecular Fluorescence, Phosphorescence, and Chemiluminescence Spectrometry

Soper¹,

McGown²,

Warner³

1994

Anal. Chem.

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“…Imidazole is one of the most useful catalysts in an aqueous PO-CL system [9]. Moreover, several studies on enhancement of PO-CL intensity in aqueous conditions by surfactants have also been reported [10][11][12].…”

Section: Introductionmentioning

confidence: 99%

Enhancement of peroxyoxalate chemiluminescence intensity by surfactants and its application to detect detergent

Wada

Abé

Ikeda

et al. 2010

Talanta

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1 Abstract Enhancement of peroxyoxalate chemiluminescence (PO-CL) intensity by a surfactant in the H 2 O 2 /bis(2,4,6-trichlorophenyl)oxalate (TCPO)/rhodamine B system was described. The effects of 15 surfactants were evaluated by comparing the ratio of a relative CL intensity (RCI) with surfactant to that of the blank in each system. In preliminary study, H 2 O 2 /imidazole-HNO 3 buffer/TCPO/rhodamine B system was used to study the effects of surfactants on PO-CL intensity. Fourteen surfactants reduced the CL intensity at the 2% concentration, where their relative CL intensities ranged from 0.6 to 93.5%. Some of these phenomena may be caused by a notable change of pH that was occurred by adding the surfactant.Additionally, enhancement of PO-CL intensity was studied by using system 1) H 2 O 2 /TCPO/rhodamine B and 2) H 2 O 2 /imidazole-HNO 3 buffer/TCPO/ systems. In the system 1, the favorable enhancement of CL intensity (ranged from 124 to 472%) was observed with 9 surfactants at the 0.5% concentration). This result suggested that several surfactants might play a role as a catalyst in the PO-CL reaction. There was no tendency to enhance CL intensity among the surfactant types. In the system 2, the enhancement of CL intensity was also observed by adding with 11 surfactants, which might be mainly caused by the fluorescent impurities of surfactants used.Furthermore, detection of detergent commercially available was applied by using the system 1.

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Chemiluminescence

Bronstein¹,

Kricka

Givens

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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Chemiluminescence is the emission of light from chemical reactions at ordinary temperatures. The reactions of chemiluminescence produce a reaction intermediate or product in an electronically excited state, and radiative decay of the excited state is the source of the light. Chemiluminescence relates to fundamental molecular interactions and transformations and its study provides access to basic elements of reaction mechanisms and molecular properties, efficient chemiluminescence can provide an emergency or portable light source, chemiluminescence provides means to detect and measure trace elements and pollutants for environmental control or clinically important substances, and classification of the bioluminescent relationship between different organisms defines their biological relationship and pattern of evolution. Liquid‐phase, gas‐phase, and solid‐phase chemiluminescence are discussed as well as bioluminescence, which is characteristic of numerous marine and a few land organisms. The applications of chemical light include marking and illumination and several types of analyses such as flow injection, hplc, direct metal, titration indicators, immunoassay, bacteria and biomass determination, and air pollution.

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Development of a chemiluminescence detection system using bis[4‐nitro‐2‐(3,6,9‐trioxadecyloxycarbonyl)phenyl] oxalate for the sensitive determination of the fluorescent compounds separated with an acidic mobile phase

Cited by 19 publications

References 27 publications

Molecular Fluorescence, Phosphorescence, and Chemiluminescence Spectrometry

Molecular Fluorescence, Phosphorescence, and Chemiluminescence Spectrometry

Enhancement of peroxyoxalate chemiluminescence intensity by surfactants and its application to detect detergent

Chemiluminescence

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