2020
DOI: 10.1021/acs.chas.0c00041
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Development of a Headspace Sampling–Gas Chromatography–Mass Spectrometry Method for the Analysis of Fireground Contaminants on Firefighter Turnout Materials

Abstract: Firefighting is classified as a 2B-possibly carcinogenic profession by the International Agency for Research on Cancer (IARC). Firefighters are exposed to a host of toxic fireground contaminants such as phenols, phthalates, and polycyclic aromatic hydrocarbons (PAHs), many of which are potentially carcinogenic. Studies show that the exposure to contaminated firefighter gear postfire poses a health risk to the firefighters. This study focused on the issue of contaminants being present on the gear and developing… Show more

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Cited by 6 publications
(3 citation statements)
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“…These results are in consonance with those observed by Shinde and Ormond [ 38 ], who optimized an HS sampling method coupled with GC-MS for the analysis of contaminants on firefighter turnout materials. So far, most of the methods used for the characterization of contaminants in firefighter PPE have been based on the identification of target compound, such as PAHs [ 14 , 22 , 23 , 24 ], making this task complex and difficult to reproduce.…”
Section: Resultssupporting
confidence: 91%
“…These results are in consonance with those observed by Shinde and Ormond [ 38 ], who optimized an HS sampling method coupled with GC-MS for the analysis of contaminants on firefighter turnout materials. So far, most of the methods used for the characterization of contaminants in firefighter PPE have been based on the identification of target compound, such as PAHs [ 14 , 22 , 23 , 24 ], making this task complex and difficult to reproduce.…”
Section: Resultssupporting
confidence: 91%
“…A custom standard containing DEHP in liquid form was run through the headspace to confirm the compound’s retention time. The details of the specific compounds and analysis are provided by Shinde et al [ 24 ].…”
Section: Methodsmentioning
confidence: 99%
“…Furthermore, the use of polymeric compounds in modern buildings and furniture can generate even more toxic substances [3,15]. Chemicals typically found in fires include, among others, aldehydes (mainly formaldehyde, and acrolein), aromatic compounds (as benzene), polycyclic aromatic hydrocarbons (PAH, as pyrene, anthracene, and benzo[a]pyrene), chlorinated hydrocarbons (as dichloromethane), as well as toxic inorganic gases (as CO, NO x , HCN, SO 2 , and HCl) known for causing acute effects [10][11][12][13][14][15][16][17][18][19][20][21].…”
Section: Introductionmentioning
confidence: 99%