Development of a highly sensitive extractive spectrophotometric method for the determination of nickel(II) from environmental matrices using N-ethyl-3-carbazolecarboxaldehyde-3-thiosemicarbazone

Ramachandraiah, C.; Kumar, J. Rajesh; Reddy, K. Pratap; Narayana, S. Lakshmi; Reddy, A. Varada

doi:10.1016/j.jenvman.2007.03.033

Cited by 14 publications

(4 citation statements)

References 7 publications

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“…Bu kalıntıya 5 mL HCl asit eklenerek tekrar kuruyuncaya kadar ısıtılmıştır. Devamında kalıntı, 100 mL de iyonize suda çözülmüş [6] ve tayin için kullanılmıştır.…”

Section: Yöntemin Analitik Uygulamalarıunclassified

Bir Hidroksiazo Bileşiği Kullanılarak Gerçek Örneklerde Nikelin Eser Miktarlarının Spektrofotometrik Tayini

Güray

2019

Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi

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Özet: Bu makalede, nikel tayini için, herhangi bir ön deriştirme işlemi uygulamadan, pH 5,5 (5-6) 'da 2,3,4,6 / -tetrahidroksi-3 / -sülfoazobenzen (THSA) ile şelat oluşturarak seçici ve duyarlı bir spektrofotometrik yöntem önerilmiştir. Metal ligand oranı 1: 1 olan kompleksin, 485 nm'de, molar absorplama katsayısı 1,60 ×10 4 L mol −1 cm −1 'dir. Kompleks bileşik 3 saat kararlılığını korumaktadır. Ayrıca, 50 C'ye kadar bozulmadan kalır. Geliştirilen yöntem 0,040-2,348 µg mL −1 Ni (II) tayin aralığında Beer'in kanununa uyar. Toprak alkali elementler, alkalin elementler, nadir toprak elementler, halojenürler, fosfatlar, askorbik asit ve katyonlar nikel tayini engellemez. Önerilen yöntem hızlı ve basittir ve nikel tayini için sertifikalı alaşımlara ve çevre suyu örneklerine kolayca uygulanabilir.Abstract: In this article, a selective and sensitive spectrophotometric by chelating with 2,3,4,6 / -tetrahydroxy-3 / -sulfoazobenzene (THSA) at pH 5.5 (5-6) without applying any preconcentration process for nickel determination method is proposed. A selective and sensitive spectrophotometric method has been proposed for the determination of nickel by forming chelate at pH 5.5 (5-6) with 2,3,4,6 /tetrahydroxy-3 / -sulfoazobenzene (THSA). Molar absorptivity of the complex having metal ligand ratio of 1:1 is 1.60 × 10 4 L mol −1 cm −1 at 485 nm. The complex compound is stable for 3 hours. Furthermore, it is stable up to 50 ° C. The developed method obeys Beer's law for 0.040-2.348 µg mL −1 Ni(II). Earth alkaline elements, alkaline elements, rare earth elements, halides, phosphates, ascorbic acid and cations do not interfere nickel determination. The proposed method is rapid and simple, and it can be easily applied on certificated alloys and environmental water samples for determining nickel.

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“…Bu kalıntıya 5 mL HCl asit eklenerek tekrar kuruyuncaya kadar ısıtılmıştır. Devamında kalıntı, 100 mL de iyonize suda çözülmüş [6] ve tayin için kullanılmıştır.…”

Section: Yöntemin Analitik Uygulamalarıunclassified

Bir Hidroksiazo Bileşiği Kullanılarak Gerçek Örneklerde Nikelin Eser Miktarlarının Spektrofotometrik Tayini

Güray

2019

Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi

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“…[10][11][12][13][14] The methods involving spectrophotometry are simple and low-cost; they can be easily combined with procedures for preliminary separation and concentration, such as cloud point extraction, 13 solid phase extraction 14 and liquid-liquid extraction (LLE). [15][16][17][18][19][20] 5-methyl-4-(2-thiazolylazo)resorcinol (MTAR) is a well-known analytical reagent. [21][22][23][24][25][26][27][28] It has recently been used in our laboratory for LLE of V IV,V .…”

Section: Introductionmentioning

confidence: 99%

Extraction-Chromogenic System for Nickel(II) Based on 5-methyl-4-(2-thiazolylazo)resorcinol and Aliquat 336

Toncheva

Hristov

Milcheva

et al. 2020

ACSi

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A water−isobutanol extraction-chromogenic system for Ni II , based on the azo dye 5-methyl-4-(2-thiazolylazo)resorcinol (MTAR; H 2 L) and the ionic liquid Aliquat 336 (A336), was studied. Under the optimal conditions (c MTAR = 2.0 × 10-4 mol dm-3 , c A336 = 5.6 × 10-3 mol dm-3 , pH 8.5 and extraction time t = 1 min), Ni II is extracted as a ternary complex which can be represented by the formula (A336 +) 2 [Ni(L 2−) 2 ]. In the absence of A336, or in a slightly acidic medium, a binary complex, [Ni(HL −) 2 ], with an absorption maximum at λ = 548 nm and a shoulder at 590 nm is formed. The following extraction-spectrophotometric characteristics were determined at the above-mentioned optimal conditions: λ max (545 nm), molar absorptivity (5.0 × 10 4 dm 3 mol-1 cm-1), Sandell's sensitivity (1.2 × 10-3 μg cm-2), Beer's law limits (0.05-3.1 µg cm-3), constant of extraction (Log K = 6.1) and fraction extracted (99.2%). The effect of foreign ions was studied; the most serious interferences were caused by Co II , Cu II and Cr III .

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“…Hence, an appropriate knowledge of the nickel content in foods could be of a great interest for the dietary control of nickeleczema patients. Several analytical techniques such as FAAS [9][10][11][12][13], GFAAS [14][15][16], ETAAS [17], AFS [18], UV-vis spectrophotometry [19][20][21][22][23][24] and ICP-OES [25,26] have been proposed for the analysis of nickel (II), but most of these require expensive equipments and time consuming sample preparation procedures. However, the electrochemical analysis of trace amounts of nickel (II) require relatively inexpensive equipment but presents certain difficulties due to their irreversible reduction behavior [27,28] of nickel.…”

Section: Introductionmentioning

confidence: 99%

Polarographic Interaction of Nickel (II) with Ammonium Piperidine-1-Carbodithioate: Application to Environmental Samples

Kanchi¹,

Bathinapatla²,

Sabela³

et al. 2014

J Environ Anal Chem

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This paper describes the interaction of nickel (II) with ammonium piperidine-1-carbodithioate (APC) using Direct Current (DC) polarography (DCP) & differential pulse polarography (DPP) at the Dropping Mercury Electrode (DME) in NH 4 Cl-NH 4 OH buffer medium at pH 6.0. The polarograms shows a predominant peak for nickel (II)-APC at-1.30 V vs SCE, indicating the production of catalytic hydrogen wave (CHW) due to electrostatic interactions between APC and nickel (II). The interactions were characterized with UV-visible spectrophotometer, FT-IR and cyclic voltammetric techniques. The developed method was applied successfully to determine the nickel (II) levels in leafy vegetables and biological samples with acceptable recoveries.

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Development of a highly sensitive extractive spectrophotometric method for the determination of nickel(II) from environmental matrices using N-ethyl-3-carbazolecarboxaldehyde-3-thiosemicarbazone

Cited by 14 publications

References 7 publications

Bir Hidroksiazo Bileşiği Kullanılarak Gerçek Örneklerde Nikelin Eser Miktarlarının Spektrofotometrik Tayini

Bir Hidroksiazo Bileşiği Kullanılarak Gerçek Örneklerde Nikelin Eser Miktarlarının Spektrofotometrik Tayini

Extraction-Chromogenic System for Nickel(II) Based on 5-methyl-4-(2-thiazolylazo)resorcinol and Aliquat 336

Polarographic Interaction of Nickel (II) with Ammonium Piperidine-1-Carbodithioate: Application to Environmental Samples

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