This paper analyzes a microwave resonator sensor based on a square split-ring resonator operating at 5.122 GHz for permittivity characterization of a material under test (MUT). A single-ring square resonator edge (S-SRR) is coupled with several double-split square ring resonators to form the structure (D-SRR). The function of the S-SRR is to generate a resonant at the center frequency, whereas D-SRRs function as sensors, with their resonant frequency being very sensitive to changes in the MUT’s permittivity. In a traditional S-SRR, a gap emerges between the ring and the feed line to improve the Q-factor, but the loss increases as a result of the mismatched coupling of the feed lines. To provide adequate matching, the microstrip feed line is directly connected to the single-ring resonator in this article. The S-SRR’s operation switches from passband to stopband by generating edge coupling with dual D-SRRs located vertically on both sides of the S-SRR. The proposed sensor was designed, fabricated, and tested to effectively identify the dielectric properties of three MUTs (Taconic-TLY5, Rogers 4003C, and FR4) by measuring the microwave sensor’s resonant frequency. When the MUT is applied to the structure, the measured findings indicate a change in resonance frequency. The primary constraint of the sensor is that it can only be modeled for materials with a permittivity ranging from 1.0 to 5.0. The proposed sensors’ acceptable performance was achieved through simulation and measurement in this paper. Although the simulated and measured resonance frequencies have shifted, mathematical models have been developed to minimize the difference and obtain greater accuracy with a sensitivity of 3.27. Hence, resonance sensors offer a mechanism for characterizing the dielectric characteristics of varied permittivity of solid materials.