Development of a new electromembrane extraction combined with ion mobility spectrometry for the quantification of malachite green in water samples

Mirzaei, Fahimeh; Nilash, Mohammadreza Mohammadi; Fakhari, Ali Reza

doi:10.1007/s12127-020-00259-y

Cited by 6 publications

(5 citation statements)

References 39 publications

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“…In this approach, an electrical field is employed as the driving force to accelerate the extraction process. [23,24] So far, EME has been utilized for the determination of various compounds, specifically drugs, [25][26][27][28] heavy metal ions, [29][30][31] amino acids, [32][33][34] peptides, [35][36][37] inorganic anions, [38] and environmental pollutants, [39][40][41] from different sample matrices.…”

Section: Introductionmentioning

confidence: 99%

Electromembrane extraction‐high‐performance liquid chromatography‐ultraviolet detection of phenobarbital and phenytoin in human plasma, saliva, and urine

Dolatabadi

Mohammadi

Nojavan

et al. 2021

J Chinese Chemical Soc

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The current article is focused on introduction and validation of electro‐membrane extraction along with a high‐performance liquid chromatography combined with UV detector for the identification of the antiepileptic drugs phenytoin (PT) and phenobarbital (PB) in plasma, saliva, and urine. In addition, 3D‐printing was utilized to fabricate the designed caps required for fixing the electrodes in the prepared setup, giving us a high potential in device fabrication with various dimensions. To arrive at the highest extraction of PB and PT, the parameters impacting the extraction efficiency of electromembrane extraction for example, supported liquid membrane composition, sample solution pH, applied voltage, extraction time along with effect of graphene oxide are examined in detail. In optimized experimental conditions, the calibration plots were obtained to be linear on the concentration range of 25–500 ng/L with the detection limit and quantitation limit of 7.5 and 25 ng/L for both of PB and PT. Relative standard deviations of <9.9% and <9.1% were found for PB and PT, respectively and the enrichment factor for the presented method was computed to be 25.4 and 44.7 for PB and PT, respectively. The proposed method was satisfactorily employed in determination of PB and PT in plasma, urine and saliva.

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Section: Introductionmentioning

confidence: 99%

Electromembrane extraction‐high‐performance liquid chromatography‐ultraviolet detection of phenobarbital and phenytoin in human plasma, saliva, and urine

Dolatabadi

Mohammadi

Nojavan

et al. 2021

J Chinese Chemical Soc

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“…Among these dyes, basic fuchsin BF is a triarylmethane dye that is inflammable and has antibacterial and fungicidal characteristics [6,7]. It is commonly employed as a colorant in textile and leather goods as well as in the staining of collagen and tubercle bacillus [8].…”

Section: Introductionmentioning

confidence: 99%

Uptake of BF Dye from the Aqueous Phase by CaO-g-C3N4 Nanosorbent: Construction, Descriptions, and Recyclability

et al. 2023

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Removing organic dyes from contaminated wastewater resulting from industrial effluents with a cost-effective approach addresses a major global challenge. The adsorption technique onto carbon-based materials and metal oxide is one of the most effective dye removal procedures. The current work aimed to evaluate the application of calcium oxide-doped carbon nitride nanostructures (CaO-g-C3N4) to eliminate basic fuchsine dyes (BF) from wastewater. CaO-g-C3N4 nanosorbent were obtained via ultrasonication and characterized by scanning electron microscopy, X-ray diffraction, TEM, and BET. The TEM analysis reveals 2D nanosheet-like nanoparticle architectures with a high specific surface area (37.31 m2/g) for the as-fabricated CaO-g-C3N4 nanosorbent. The adsorption results demonstrated that the variation of the dye concentration impacted the elimination of BF by CaO-C3N4 while no effect of pH on the removal of BF was observed. Freundlich isotherm and Pseudo-First-order adsorption kinetics models best fitted BF adsorption onto CaO-g-C3N4. The highest adsorption capacity of CaO-g-C3N4 for BF was determined to be 813 mg. g−1. The adsorption mechanism of BF is related to the π-π stacking bridging and hydrogen bond, as demonstrated by the FTIR study. CaO-g-C3N4 nanostructures may be easily recovered from solution and were effectively employed for BF elimination in at least four continuous cycles. The fabricated CaO-g-C3N4 adsorbent display excellent BF adsorption capacity and can be used as a potential sorbent in wastewater purification.

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“…Electro‐membrane extraction (EME) technique was introduced in 2006 as a new modification to the microextraction process by utilizing potential as the driving force (Magnus et al, 2020). EME is an electroanalytical microextraction method that requires a small amount of the acceptor phase supported by a porous hollow fiber membrane to extract the target analytes (Fahimeh et al, 2020; Bjergaard et al, 2017). In EME, a conductive solvent was coated on the porous membrane walls.…”

Section: Introductionmentioning

confidence: 99%

“…In EME, a conductive solvent was coated on the porous membrane walls. The applied electric field to the electrodes (platinum wire) immersed in the sample solution (donor phase) is used to accelerate the migration of the target analyte from this phase toward the supported membrane that works as an acceptor phase (Astrid & Stig, 2011; Behpour et al, 2020; Fahimeh et al, 2020; Magnus et al, 2020).…”

Section: Introductionmentioning

confidence: 99%

“…Previous reported studies indicated that it is one of the aromatic plants belonging to the Lamiaceae family (Coelho et al, 2018; Kusuma & Mahfud, 2016), which contains many chemical compounds that include ~150 species (Coelho et al, 2018; Güez et al, 2017). These compounds are used in cooking, flavors, toothpaste preparation, perfumery, medicine, cosmetics, and food industry (Bjergaard et al, 2017; Chenni et al, 2016; Fahimeh et al, 2020; Magnus et al, 2020; Moura et al, 2020; Nidia et al, 2013; Saha et al, 2012).…”

Section: Introductionmentioning

confidence: 99%

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Biosynthesized silver nanoparticle–coated electro‐membrane extraction of perchlorate in different seafood samples

Amayreh

Basheer

Abdullah

et al. 2021

Biomedical Chromatography

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In this work we developed a rapid and straightforward technique in which biosynthesized silver nanoparticles (Ag‐NPs) were coated on a porous membrane utilizing electrical potential to extract perchlorate from seafood samples. The biosynthesized Ag‐NPs were well characterized using UV–Vis. spectrophotometry, X‐ray diffraction, and scanning electron microscopy. After extraction, analyses were performed using ion chromatography. The Ag‐NP‐coated porous polypropylene membrane shows higher extraction efficiency due to the high electrical conductivity of the Ag‐NPs. The performance of this efficient technique was compared with those previously reported in the literature. The extraction variables that affect extraction of the target analyte and influence percentage recovery, such as pH of the sample solution, extraction time, and applied voltage, were investigated and optimized. The results demonstrated optimum conditions to achieve low detection limits [LODs (limits of detection)]: sample solution (pH = 6), short extraction time (10 min), and applied voltage (5 V). The developed method shows excellent linearity for perchlorate ion in the range from 0.001 to 350 μg L−1 with a coefficient of determination (r2) of 0.9991. The detection limit (LODs) and quantification limits (limits of quantification) were found to be 0.04 and 0.1225 μg kg−1, respectively. The mean recovery percentages for three replicates of 10 different spiked fish samples by 3 μg g−1 of perchlorate were between 92.2 and 106.2%, with an observed relative standard deviation in the range of 0.8–3.7%. The proposed method is rapid, sensitive, inexpensive, environmentally friendly, and highly effective in extracting perchlorate from different seafood samples.

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Development of a new electromembrane extraction combined with ion mobility spectrometry for the quantification of malachite green in water samples

Cited by 6 publications

References 39 publications

Electromembrane extraction‐high‐performance liquid chromatography‐ultraviolet detection of phenobarbital and phenytoin in human plasma, saliva, and urine

Electromembrane extraction‐high‐performance liquid chromatography‐ultraviolet detection of phenobarbital and phenytoin in human plasma, saliva, and urine

Uptake of BF Dye from the Aqueous Phase by CaO-g-C3N4 Nanosorbent: Construction, Descriptions, and Recyclability

Biosynthesized silver nanoparticle–coated electro‐membrane extraction of perchlorate in different seafood samples

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