Abstract:The phase transformations in the Al-Ca-Mg-Si system have been studied using thermodynamic calculations and experimental methods. We show that at 10% Magnesium (Mg), depending on the concentrations of calcium (Ca) and silicon (Si), the following phases crystallize first (apart from the aluminum (Al) solid solution): Al 4 Ca, Mg 2 Si, and Al 2 CaSi 2 . We have found that the major part of the calculated concentration range is covered by the region of the primary crystallization of the Al 2 CaSi 2 phase. Regardless of the Ca and Si content, the solidification of the aluminum-magnesium alloys ends with the following nonvariant eutectic reaction: L → (Al) + Al 4 Ca + Mg 2 Si + Al 3 Mg 2 . With respect to the temperature and composition of the liquid phase, this reaction is close to the eutectic reaction in the Al-Mg binary system. The addition of Ca and Si to the Al-10% Mg base alloy increases its hardness, reduces its density, and has no negative influence on its corrosion resistance. We have also established that the near-eutectic alloy containing about 3% Ca and 1% Si has the optimum structure.