Low-temperature thermal desorption, in which thermal energy is used to vaporize and physically
separate volatile and semivolatile organic contaminants from soil, is among the most promising
and economic ex situ soil remediation alternatives. Experiments were performed using a bench-scale thermal desorber, the batch thermal reactor, which was developed as a prototype to
commercial desorbers. A treatability study using four representative samples of industrial
contaminated soil was followed by a fundamental study of the thermal desorption process using
three controlled samples prepared by mixing a soil with binary mixtures of selected polynuclear
aromatic hydrocarbons. For the industrial samples, the effect of desorber residence time,
temperature, and several pretreatments on contaminant removal was investigated. Three of
the five samples were successfully treated to the legislated soil remediation limits. Using the
prepared samples, the effects of sample porosity, contaminant molar mass, desorber residence
time, and temperature on thermal desorption were investigated. The experimental results were
fitted to an exponential desorption equation, and the desorption rate curves were generated to
provide a basis for scale-up.