A P23 weld metal showed a severe intergranular cracking at elevated temperatures. This reaction results from the strong segregation of impurities at the grain boundary carbide interfaces and the decrease in the bulk content of W which arises from the partitioning of W into carbides. Meanwhile, the other P23Mo weld metal containing 0.5 wt.% Mo showed a considerable ductility under the same conditions. The primary reasons for this result are the intrinsic grain boundary strengthening effect of Mo and the suppression of both the Fe 2 W Laves phase formation and the partitioning of W into carbides.