This paper reports on the design and analysis of a capacitive vibration-to-electrical energy converter. A theoretical design model of a parallel-plate electrostatic springmass-system is presented, based on state space equations. The charging of the parallel-plate capacitor takes place by utilizing materials with different work functions for the electrodes. Numerical simulations are performed in order to optimize design parameters targeting a maximum output power. Such a Micro-Electro-Mechanical System (MEMS) based capacitive energy converter is able to provide an output power of 4.28 µW at an external vibration with a frequency of 1 kHz and an amplitude of 1.96 m/s 2 (0.2 g). This corresponds to a power density of 79.26 µW/cm 3 based on a typical MEMS die size.