<div>The twin challenges of the automotive industry namely petroleum dependence and
environmental pollution paved way for the development of an environmentally
friendly and feasible substitute for diesel, possessing power characteristics
equivalent to those of a diesel engine. Biofuel has potential as a renewable
energy source, offering a more sustainable alternative to traditional fossil
fuels. However, it does come with some challenges, such as varying quality and
combustion properties. To enhance its performance, engines can be fine-tuned by
adjusting fuel injection parameters, such as timing, pressure, and duration.
Accordingly, this research article focuses on optimizing the fuel injection
parameters for a CRDi engine powered by D+LPO (20% lemon peel oil and 80%
diesel) biofuel, with the goal of improving both performance and emission
characteristics. The experimental design matrix was generated using Design
Expert-13 software, employing the I-optimal technique. Utilizing response
surface methodology, a higher-order regression relationship is formulated for
engine output performance and emissions response. The engine response matrix is
developed with higher-order fit model (R<sup>2</sup>) for the entire operating
speed and torque operations under various fuel injection operating points. The
results obtained as, for better BTE, D+LPO maintained a higher quantity of pilot
mass than diesel, which is identified as 22–26% for D+LPO and 10–16% for diesel.
The combustion quality of D+LPO was increased with homogeneity of the air–fuel
mixture, which was improved by the advanced pilot injection. At lower speeds
higher injection pressure and at higher speeds lower injection pressure is
identified for diesel than D+LPO.</div>