Development of Easily Separable ZnO‐Supported Au Nanocatalyst for the Oxidative Esterification of Alcohols and Reduction of Nitroarenes

Abstract

A simple and practical protocol is described for the reduction of aromatic nitro compounds and the oxidative esterification of alcohols by using a recyclable 3D assembled porous rectangular ZnO nanoplates supported gold nanocatalysts (Au/ZnO) under mild conditions. The support 3D assembled ZnO plate was synthesized simple strategy without employing any toxic reductants or capping agents and Au was loaded through simple impregnation method. The synthesized catalyst was characterized by powder X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), electron microscopic study (TEM & SEM), diffuse reflectance spectrum (DRS). The developed catalyst showed excellent catalytic activity for both the reaction and ended with good to excellent yield, up to 97% yield for nitro reduction and 90% yield for oxidative esterification. The catalyst is recyclable for a minimum five times without any significant loss in catalytic activity. The catalytic activities are superior or sometime comparable to that of the reported catalyst. The use of a developed catalyst is beneficial for of low cost and availability of good support ZnO and advantageous with respect to that of separation, easily separable by simple filtration due to the bigger size of support ZnO.

Applications of Metal/Metal Oxides Nanoparticles in Organic Transformations

“…Similarly, reduction of aromatic nitro compounds and their esterification reaction were reported by Galani et al [53]. A modest and real-world procedure is proposed for the reduction of aromatic nitro compounds and the oxidative esterification of alcohols by using a recyclable 3D assembled porous rectangular ZnO nanoplatelets supported gold nanocatalysts (Au/ZnO) under mild conditions.…”

“…Moreover, the catalyst was recyclable for a minimum of five times lacking some noteworthy loss in catalytic property. The expenditure of the technologically advanced catalyst was advantageous because of the less expensive and accessibility of the ZnO support and beneficial with respect to catalyst recovered by simple filtration of the ZnO based nanostructured materials [53,54]. Giri et al developed rectangular ZnO porous assembly with admirable catalytic activity.…”

Transition Metal-Based Nanoparticles Catalyzed Esterification Reactions

“…Applications of esters have been dealt with in detail in section 8. 3,5,6 Fischer esterification, named after 1902 Nobel laureate in Chemistry, Hermann Emil Fischer, is a reversible acidcatalyzed condensation reaction and the most common method of esterification. 1 It requires the use of strongly acidic conditions.…”