Cell(s) voltage and power density of solid oxide fuel cell (SOFC) depend on testing conditions such as gas composition and flowrate and operation temperatures as well as cell materials and designs themselves. A safe and precise method was developed to generate reformate-model-gases corresponding to various raw fuels of SOFC system (CH 4, kerosene, diesel etc.) and reforming reactions at wide range of S/C, O 2 /C, and temperatures. It was confirmed that the reformate-model-gases can be precisely produced over a Ni catalyst using H 2 -O 2 -CO 2 -(N 2 ) or H 2 -CH 4 -CO 2 -N 2 mixtures as feedstock. Flow-rate calibration of the feedstock could realize uncertainties of the model-gas compositions and flow-rates at a level of ±1.0 mol.% for H 2 and H 2 O, ±0.5 mol.% for CO, CO 2 , and CH 4 , and ±1.1% for total flowrate of the model reformates.