34th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit 1998
DOI: 10.2514/6.1998-3662
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Development of equation-of-state and transport properties for molecular plasmas in pulsed plasma thrusters. II - A two-temperature equation of state for Teflon

Abstract: The chemical composition of tetratluoroethylene (C,F,) is calculated with a two-temperature LTE formulation. Twenty-five chemical species are included in the analysis. The equilibrium constants are calculated using the most recent spectroscopic data available. Calculations are performed for pressures from 0.001 atm to 1.0 atm and for temperature ranges of 0.05 ev to 10 ev for both heavy particle and electron temperatures.

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Cited by 7 publications
(7 citation statements)
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“…Having calculated the plasma density and electron temperature (Eqs. 1-3) one can calculate the chemical plasma composition considering Local Thermodynamic Equilibrium (LTE) in the way described previously 18,19 . In the considered range of electron temperature (1-2 eV) and plasma density (10 24 -10 26 m -3 ) it is assumed that polyatomic molecules C 2 H 4 are fully dissociated and we will start our consideration from the point when we have a gas containing atoms of C and H. The distribution of the atoms, multiply ionized ions, and electrons obeys the corresponding Saha equation.…”
Section: The Ablation-controlled Discharge Modelmentioning
confidence: 99%
“…Having calculated the plasma density and electron temperature (Eqs. 1-3) one can calculate the chemical plasma composition considering Local Thermodynamic Equilibrium (LTE) in the way described previously 18,19 . In the considered range of electron temperature (1-2 eV) and plasma density (10 24 -10 26 m -3 ) it is assumed that polyatomic molecules C 2 H 4 are fully dissociated and we will start our consideration from the point when we have a gas containing atoms of C and H. The distribution of the atoms, multiply ionized ions, and electrons obeys the corresponding Saha equation.…”
Section: The Ablation-controlled Discharge Modelmentioning
confidence: 99%
“…The following equations are the (9) reactions considered in this model that constitute the reaction path, as shown in Table II. 17) Writing these reactions in terms of equilibrium relations for the partial pressures.…”
Section: Thermochemical Modelmentioning
confidence: 99%
“…Having calculated the plasma density and plasma temperature (Eqs. 1-3) one can calculate the chemical plasma composition considering Local Thermodynamic Equilibrium (LTE) in the way described previously 8,9,12,13 . We start our consideration from the point when we have a gas At the power density level of 10 10 Wm -2 realized in the micro-laser plasma thruster 1 , the main mechanism of plasma absorption and therefore electron heating is the inverse bremsstrahlung.…”
Section: Figure 2 Schematic Of the Model In T-mode (Not To Scale)mentioning
confidence: 99%