We have studied scintillation properties of Eu3+-doped Gd3Al2Ga3O12 single crystals. Gd3Al2Ga3O12 single crystals with different concentrations of Eu3+ (0.5, 1.0, 5.0, 10.0, and 15.0 %) were grown using the floating-zone method. In photoluminescence (PL) and scintillation properties, the Eu-doped Gd3Al2Ga3O12 single crystals showed emission peaks and several millisecond decay times due to 4f-4f transitions of Eu3+ ions. Pulse height spectra of all the samples were investigated under γ-ray irradiation from 137Cs (662 keV). The 0.5, 1.0, 5.0, and 10.0 % Eu-doped samples showed full energy peaks. Among all the samples, the 5.0 % Eu-doped Gd3Al2Ga3O12 single crystal showed the highest light yield of 36,000 photons/MeV.