Energy performances of new amine-based solvents were evaluated in this chapter by three different approaches; a plant test in a 1 t -CO2 /d facility, a heat and mass balance analysis based on an equilibrium stage model and a process simulation with Aspen Plus®. The solvents were amine aqueous solutions (Solvent A and Solvent B) developed by RITE in formulation of amine mixtures with 2-Isopropylaminoethanol and additives. A thermal energy requirement to regenerate a solvent in CO 2 removal from blast furnace gas, which was 20 kPa -CO2 in partial pressure, was evaluated in the analyses. The results of the plant test show that thermal energy requirements of Solvent A and Solvent B at the 90% CO 2 recovery were 3.6 GJ/t -CO2 and 4.0 GJ/t -CO2 respectively. Also, the heat and mass balance analysis of equilibrium condition estimates 2.48 GJ/t -CO2 for Solvent A and 2.33 GJ/t -CO2 for Solvent B. To evaluate a potential of each solvent, the process simulation was done in consideration of the optimized process condition, such as installing an intercooler in an absorber and assuming low heat loss from equipments. The result shows that both Solvent A and Solvent B can lead to excellent energy performance of 2.5~2.6 GJ/t -CO2 .