The efficient selection of an almost pure single harmonic emission (the 14th harmonic at 57 nm) from the harmonic comb has been experimentally achieved in an argon gas cell using a multi-color laser field with an aperture-iris diaphragm. When compared with the nondiaphragm case, the purity of the selected single harmonic emission (i.e. the contrast ratio) in the case of using the aperture-iris diaphragm is dramatically increased by approximately order of magnitude. Therefore, the modification of the multi-color laser field by using such an aperture-iris diaphragm before focusing is demonstrated to be an effective way of improving the phase-matching conditions for selective enhancement of the single harmonic emission.