This study is to evaluate the radiation properties of coal char and ash particles. Char in coal-ring and gasi cation processes exists in the form of heterogeneous composite particles consisting of nano-order ne particles made mainly of soot and micron-order particles of carbon and ash components. The radiation properties are discussed in terms of apparent extinction e ciency determined from spectra of transmissivity of a particle-liquid para n wax dispersion lm as an independent parameter of particle dispersion density. Extinction e ciency measured directly from the original char gives an unacceptably great magnitude. However, if the original char was classi ed into a narrow particle size distribution by pretreatment with a wet method, the extinction e ciency of each particle showed a reasonable magnitude and successfully deduced an extinction coe cient of the original char dispersion with a certain content from combining that of each particle accounting for the fraction. The e ect of carbon content in char particle excluding soot on extinction efciency could also be correlated empirically by a simple function using the properties of carbon-free ash burnt out and ash-free carbon treated by hydro uoric acid. Additionally, the value of apparent extinction e ciency measured from transmissivity of ash dispersion was compared with the properties estimated by applying the known refractive index into Mie's theory, and noted to be closer to rather absorption e ciency than the extinction e ciency analyzed theoretically, although scattering albedo was as large as over 0.9. This fact may result in that a strong forward scattering pointed out in a previous work was reasonable and the ash particle cloud can be assumed as an absorbing-emitting medium having the properties obtained here, ignoring the e ect of scattering at least.