Development of Recent Total Syntheses Based on the Heck Reaction

Heravi, Majid M.; Hashemi, Elaheh; Ghobadi, Nazanin

doi:10.2174/13852728113179990032

Cited by 61 publications

(24 citation statements)

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“…We also are kin to update the applications of name reactions in the total synthesis of natural products [118][119][120][121][122][123][124][125][126][127][128] and applications of different synthons, reagents and catalysts in organic synthesis [129][130][131][132][133][134][135] .…”

Section: Introductionmentioning

confidence: 99%

Isocyanide-based multicomponent reactions in the synthesis of heterocycles

2016

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Section: Introductionmentioning

confidence: 99%

Isocyanide-based multicomponent reactions in the synthesis of heterocycles

2016

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“…Palladium belongs to the noble metals group of the transition series that plays an important role in materials and chemistry . Coupling reactions including Suzuki‐Miyaura, Buchwald‐Hartwig amination, Heck and Sonogashira reactions have become a routine for organic chemists all over the world, utilizing Pd 2+ ions . Due to the increasing use of palladium salts in these reactions, residual palladium is released into the environment at an alarming rate .…”

Section: Methodsmentioning

confidence: 99%

A Bispyrazole Based Porous 2D Luminescent MOF for the Turn‐Off Detection of Pd(II) Ions

et al. 2019

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A novel bispyrazole based porous MOF ({[Zn(MBPz)(Ene)0.5]⋅2DMF⋅2H2O}n (1)) with open alkene (‐HC=CH‐) and nitrogen sites has been synthesized, as an efficient fluorescent sensor for Pd(II) ions. The MOF exhibits 3D supramolecular structure with open channels having 27.2% porosity. The unsaturated ‐CH=CH‐ moieties are present along the walls of open channels which is favorable for interaction with guest moieties. The cation sensitivity of 1 was evaluated using a series of transition metal ions in DMF. The fluorescence quenching of 1 was demonstrated by an approximately 94% reduction in the emission intensity upon binding to Pd2+ ions. The emission intensity of 1 at 414 nm has shown a linear response to Pd(II) ion concentration with a detection limit of 4.7 x 10−7 M. The sensing property of 1 towards Pd(II) ions is attributed to the π electron donation from the alkene bonds present in the ligand (Ene).

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“…In recent years, our research group showed interest and focused on the applications of name reactions in the total synthesis of natural products . Among them, in 2012 we published a report, covering the applications of SMCR in the total synthesis of natural products in Tetrahedron, which has seemingly attracted much attention of synthetic organic chemists due to numerous citations it has gained till date.…”

Section: Introductionmentioning

confidence: 99%

Current Applications of Suzuki–Miyaura Coupling Reaction in The Total Synthesis of Natural Products: An update

Koshvandi

Heravi

Momeni

2018

Applied Organom Chemis

168

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Suzuki‐Miyaura Coupling Reaction (SMCR) has been extensively used in the total synthesis of natural products. We underscored these achievements in a report published in Tetrahedron up to 2012. Since then, there has been tremendous growth in this field and numerous articles have been published after 2012. In this review, we tried to go insight and highlight the current developments in the applications of SMCR as a key and strategic step (steps) in the total synthesis of biologically active natural products accomplished and reported from 2012 till date.

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Development of Recent Total Syntheses Based on the Heck Reaction

Cited by 61 publications

References 0 publications

Isocyanide-based multicomponent reactions in the synthesis of heterocycles

Isocyanide-based multicomponent reactions in the synthesis of heterocycles

A Bispyrazole Based Porous 2D Luminescent MOF for the Turn‐Off Detection of Pd(II) Ions

Current Applications of Suzuki–Miyaura Coupling Reaction in The Total Synthesis of Natural Products: An update

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