It is widely accepted that a proper structural modularity degree of assembly processes in terms of mass customization has a positive effect on their efficiency because it, among other things, increases manufacturing flexibility and productivity. On the other hand, most practical approaches to identify such a degree is rather based on intuition or analytical reasoning than on scientific foundations. However, the first way can be used for simple assembly tasks, but in more complex assembly processes, this method lags behind the second. The purpose was to create a methodology for selection of optimal modular assembly model from among a predefined set of alternatives. The methodology is based on exploration of the relations between modularity measures and complexity issues as well as the relationship between structural modularity and symmetry. Especially, the linkage between modularity and complexity properties has been explored in order to show how modularization can affect distribution of the total structural complexity across the entire assembly line. To solve this selection problem, three different methods are preliminary suggested and compared via a series of numerical tests. The two of them present the novel contribution of this work, while the third method developed earlier for the purpose of finding and evaluating community structure in networks was adapted for a given application domain. Based on obtained results, one of these method is prioritized over another, since it offers more promising results and precision too.