Due to increasing growth population and energy demand, energy harvesting technology has become a sensational research topic. Harvesting waste heat has gained significant interest because of its cost effectiveness and availability of significant thermal fluctuations in industrial processes as well as in nearby surroundings. In the present study, the pyroelectric lead zirconium titanate (PZT) thick films grown using modified sol-gel approach have been used for pyroelectric energy conversion. The effect of annealing temperature (450, 450, and 650°C) on the growth of PZT films has been monitored by investigating their dielectric, ferroelectric, and pyroelectric properties. An appreciable enhancement in saturation and remnant polarizations from 17µC/cm2 to 24µC/cm2 (P_s) and 13µC/cm2 to 22µC/cm2 (P_r) has been obtained when annealed temperature is increased from 550 to 650°C, respectively. The pyro electric coefficient and figure of merit are found to increase from 25x10-3 Cm-2K-1 to 230x10-3 Cm-2K-1 (p) and from 2.2 m2C-1to 20 m2C-1 for the optimized PZT thick film based pyroelectric device with increase in the external DC bias field from 0.5 to 2.5 V. The enhanced results of pyroelectric coefficient and figure of merit achieved are good indication of electrical energy harvesting.