Three 1.3 GHz 9-cell large grain superconducting niobium cavities were experimented with the proposal of medium temperature baking, using buffered chemical polishing to remove the previous heat treatment impurity profiles. 2 K vertical tests of the cavities gave the average intrinsic quality factor of 2.7×1010 at 16 MV/m, as well as the maximum accelerating gradients of 20-22 MV/m. These promising values confirmed the effectiveness of an improved medium temperature baking recipe for niobium cavities which have been benefitting the superconducting radiofrequency community. Furthermore, the resistance analysis demonstrated that medium temperature baking reduced both the BCS resistance and the residual resistance of the cavities. Impurity analysis on niobium samples provided some proof that the former reduction was due to the shortened electron mean free path, while the later reduction was probably correlated with the mitigation of the increased interstitial impurity atoms.