DFT stimulation and experimental insights of chiral Cu(ii)–salen scaffold within the pocket of MWW-zeolite and its catalytic study

Abstract

A Cu(II)-salen complex encapsulated in MWW-framework as an efficient chiral organocatalyst was developed for the synthesis of 3,4-dihydropyrimidin-2-(1H)-one (DHPMs) derivatives via an asymmetric pathway. In order to confirm its structural...

Efficient Visible Light Active Photocatalyst: Magnesium Oxide-Doped Graphitic Carbon Nitride for the Knoevenagel Condensation Reaction

“…This improvement can be attributed to the increased electron diffusion mobility within MgO@g-C 3 N 4 , which facilitates faster and more efficient interfacial charge carrier transfer, which is crucial for effective photocatalysis. These results highlight the enhanced electronic properties of MgO@g-C 3 N 4 , providing further support for its superior photocatalytic performance. − …”

Graphitic carbon nitride (g-C3N4) as an emerging photocatalyst for sustainable environmental applications: a comprehensive review

“…Water scarcity, pollution, and the depletion of fossil fuels have compelled humanity to explore novel technologies that mitigate these issues while minimizing environmental harm. [13][14][15][16] Photocatalysis, as an eco-friendly and energy-efficient process, has emerged as a ray of hope. 17,18 By exploiting semiconductor materials that can absorb solar radiation and catalyze chemical reactions, photocatalysis has the potential to transform pollutants into harmless byproducts, produce clean energy from sunlight, and address the daunting issue of global warming through carbon capture and utilization.…”

Sustainable approach for the synthesis of chiral β-aminoketones using an encapsulated chiral Zn(ii)–salen complex

“…8 Owing to this new challenge, organic synthesis has become increasingly popular under solvent-free conditions, as “green chemistry” strives to minimize pollution, costs, and tedious procedures. 9,10…”