Di- and triorganotin(IV) carboxylates derived from triorganotin(IV) iodide with mixed organic groups on tin: Cyclic, hexameric triorganotin(IV) carboxylates

Amini, Mostafa M.; Azadmehr, Amirreza; Alijani, Vajiheh; Khavasi, Hamid Reza; Hajiashrafi, Taraneh; Kharat, Ali Nemati

doi:10.1016/j.ica.2008.04.009

Cited by 43 publications

(23 citation statements)

References 30 publications

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“…The O-Sn-O angles in 3, [Sn1, 178.03(15)°; Sn2, 176.82(14)°] are different from each other. The O-Sn-O skeleton, with average angle of 177.425°, is similar to that of [EtPh 2 SnOC(O)CH 3 ][37], and is bent and slightly larger than that of di-and triorganotin carboxylates with hexameric structure[38]. The sum of the C-Sn-C bond angles in 3 (Sn1, 359.3°; Sn2, 359.1°) is close to ideal (360°).…”

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confidence: 82%

Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Zhang

et al. 2011

J Inorg Organomet Polym

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Four new organotin (IV) complexes of two types [(R 2 Sn) 2 (C 7 H 10 O 4 )(l 3 -O)] n (R = Me: 1; nBu: 2; and {(R 3 Sn) 2 [C 5 H 10 (COO) 2 ]} n (R = Me: 3; nBu: 4) have been synthesized by the reaction of 3-methyladipic acid with the corresponding R 3 SnCl (R = Me, nBu) under two different experimental conditions. All the complexes were characterized by elemental analysis, FT-IR, and NMR ( 1 H, 13 C, 119 Sn) spectroscopy. Except for 2, all of the complexes were also characterized by X-ray crystallography. The structural analyzes show that complex 1 is a 1D infinite chain polymer and forms a 2D organotin framework through intermolecular C-HÁÁÁO interactions and weak SnÁÁÁO interactions. Complexes 3 and 4 are 2D network polymers in which 3-methyladipic acid acts as a tetra dentate ligand coordinated to the trialkyltin (IV) ion.

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confidence: 82%

Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Zhang

et al. 2011

J Inorg Organomet Polym

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“…大量的研究结果表明, 三烃基锡化合物的生物活性与锡原子上烃基的种类有关 [1][2][3] ; 并且对于分子中同时含有环己基、丁基或苯基的混合三烃基锡化合物, 则可能既有杀菌活性, 又有杀螨活性 [4,5] . 杨志强等在对 Bu n Cy 3-n SnX 类化合物研究中, 发现其杀虫和杀菌随着 n 的变化而变化, 当 n＝2 时, 这类化合物同时兼有较高的杀菌和杀螨活性 [6] .…”

Section: 许多三烃基锡化合物由于具有一定的生物活性已被广泛作为杀螨剂、杀虫剂和杀菌剂应用于农业生产中如杀菌剂薯瘟锡(三unclassified

Syntheses and Characterization of Cyclohexyl(phenyl)-[(trimethylsilyl)methyl]stannyl Aromatic Carboxylates

龚根飞¹,

宋冉²,

邹引波³

et al. 2013

Chin. J. Org. Chem.

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“…In fact, organotin(IV) complexes are extensively studied due to its coordination geometries as well as structural diversity (monomer, dimer, hexamer and oligomer). [24][25][26] Organotin(IV) compounds are well known to form complexes with ligands having oxygen, 27 sulfur 28 and nitrogen 29 donor sites.…”

Section: Introductionmentioning

confidence: 99%

Dialkyltin(IV)bis(O–tolyl/benzyldithiocarbonate) complexes: Spectroscopic, thermogravemetric, antifungal and crystal analysis of n–Bu2Sn(S2COCH2C6H5)2

Gupta¹,

Kumar²,

Kalgotra³

et al. 2015

ACSi

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Novel compounds of dimethyl-and dibutyltin(IV) with O-tolyl/benzyldithiocarbonatesSn) spectroscopy. The thermal behaviour of the complex 8 has been studied by TGA/DTA analysis. The complex [(n-Bu) 2 Sn(S 2 COCH 2 C 6 H 5 ) 2 ] (8) crystallizes in the monoclinic space group C2/c, in which tin adopts a distorted octahedron or skew trapezoidal bipyramidal geometry accompanied by two n-butyl chains and the two dithiocarbonate ligands coordinated in an anisobidentate fashion. Antifungal activities against fungus Fusarium sp. of these organotin(IV) derivatives exhibited enhanced activity compared to the free ligands.

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Di- and triorganotin(IV) carboxylates derived from triorganotin(IV) iodide with mixed organic groups on tin: Cyclic, hexameric triorganotin(IV) carboxylates

Cited by 43 publications

References 30 publications

Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Syntheses and Characterization of Cyclohexyl(phenyl)-[(trimethylsilyl)methyl]stannyl Aromatic Carboxylates

Dialkyltin(IV)bis(O–tolyl/benzyldithiocarbonate) complexes: Spectroscopic, thermogravemetric, antifungal and crystal analysis of n–Bu2Sn(S2COCH2C6H5)2

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