2007
DOI: 10.1107/s1600536807061478
|View full text |Cite
|
Sign up to set email alerts
|

Di-μ3-iodido-diiodidobis(μ2-4′-phenyl-2,2′:6′,2′′-terpyridine)tetracopper(I)

Abstract: The title complex, [Cu4I4(C21H15N3)2], lies on an inversion centre located at the centroid of a four-membered ring formed by one of the crystallographically independent CuI ions and a triply bridging iodide ligand. The 2,2′:6′,2′′-terpyridine (phterpy) ligand chelates each of the independent CuI centres in a bidentate fashion, with the N atom of the central pyridyl ring bridging the two CuI centres and those of the outer pyridyl rings binding the two independent CuI ions individually to form a dinuclear system… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1

Citation Types

0
3
0

Year Published

2010
2010
2019
2019

Publication Types

Select...
3

Relationship

0
3

Authors

Journals

citations
Cited by 3 publications
(3 citation statements)
references
References 7 publications
0
3
0
Order By: Relevance
“…of terpyridine is added to 4, the unusual bimetallic species 5 can be isolated reproducibly, thus providing a snapshot of the ligand substitution reaction. Terpyridine is known to bind to more than one metal center, [21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36] however such nickel adducts are unknown.…”
mentioning
confidence: 99%
“…of terpyridine is added to 4, the unusual bimetallic species 5 can be isolated reproducibly, thus providing a snapshot of the ligand substitution reaction. Terpyridine is known to bind to more than one metal center, [21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36] however such nickel adducts are unknown.…”
mentioning
confidence: 99%
“…For related complexes with phtpy as a ligand, see: Chen et al (2005); Constable et al (1990); Hou & Li (2005); Rao et al (1997); Shi et al (2007); Tu et al (2004); Xie et al (2008).…”
Section: Related Literaturementioning
confidence: 99%
“…Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL. 4′-Phenyl-2,2′:6′,2"-terpyridine (phtpy) is an excellent chelating ligand and arising from its good coordinating abilities with a broad variety of transition metal ions, such as Cu I , Ag I , Mn II , Ni II , Cu II , Zn II and Ru II metal ions, it has recently been the focus of several investigations (Chen et al, 2005;Constable et al, 1990;Hou & Li, 2005;Rao et al, 1997;Shi et al, 2007;Tu et al, 2004;Xie et al, 2008). Some of the reported complexes exhibit interesting photoluminescent and magnetic properties.…”
Section: Data Collectionmentioning
confidence: 99%