2024
DOI: 10.1021/jacs.4c04370
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Di-π-ethane Rearrangement of Cyano Groups via Energy-Transfer Catalysis

Yu Zheng,
Qi-Xin Dong,
Shu-Ya Wen
et al.

Abstract: Molecular rearrangement occupies a pivotal position among fundamental transformations in synthetic chemistry. Radical translocation has emerged as a prevalent synthetic tool, efficiently facilitating the migration of diverse functional groups. In contrast, the development of di-π-methane rearrangement remains limited, particularly in terms of the translocation of cyano functional groups. This is primarily attributed to the energetically unfavorable three-membered-ring transition state. Herein, we introduce an … Show more

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Cited by 12 publications
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