2020
DOI: 10.1107/s2056989020009834
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Diaquabis{μ-1,5-bis[(pyridin-2-yl)methylidene]carbonohydrazide(1–)}di-μ-chlorido-tetrachloridotetrazinc(II)

Abstract: A tetranuclear ZnII complex, [Zn4(C13H11N6O)2Cl6(H2O)2] or {[Zn2(HL)(H2O)(Cl2)](μCl)2[Zn2(HL)(H2O)(Cl)]}2, was synthesized by mixing an equimolar amount of a methanol solution containing ZnCl2 and a methanol solution containing the ligand H2 L [1,5-bis(pyridin-2-ylmethylene)carbonohydrazide]. In the tetranuclear complex, each of the two ligand molecules forms a dinuclear unit that is connected to another dinuclear unit by two bridging chloride anions. In each dinuclear unit, one ZnII cation i… Show more

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“…"It has been reported in the literature that dicarbonohydrazone with their cis-enol conformations or cis-enol and trans association lead to square or rectangular grid polynuclear complexes, respectively, with interesting physical properties" [23]. In these coordination compounds, the dicarbonohydrazone act as  2 -O [24,25,26] and/or  2 -N-N bridged pentadentate or hexadentate ligand [37][38][39][40]. Depending on their tridentate or tetradentate behavior, monocarbonohydrazide yield, generally, mononuclear or dinuclear complexes with transition metal ions [21].…”
Section: Introductionmentioning
confidence: 99%
“…"It has been reported in the literature that dicarbonohydrazone with their cis-enol conformations or cis-enol and trans association lead to square or rectangular grid polynuclear complexes, respectively, with interesting physical properties" [23]. In these coordination compounds, the dicarbonohydrazone act as  2 -O [24,25,26] and/or  2 -N-N bridged pentadentate or hexadentate ligand [37][38][39][40]. Depending on their tridentate or tetradentate behavior, monocarbonohydrazide yield, generally, mononuclear or dinuclear complexes with transition metal ions [21].…”
Section: Introductionmentioning
confidence: 99%