Dichloridobis[3-(4-chlorophenyl)-2,N,N-trimethyl-2,3-dihydro-1,2,4-oxadiazole-5-amine-κN⁴]platinum(II)–4-chlorobenzaldehyde (1/1)

Abstract

In the title 1:1 co-crystal, [PtCl2(C11H14ClN3O)2]·C7H5ClO, the coordination polyhedron of the PtII atom is slightly distorted square-planar with the chloride and 2,3-di­hydro-1,2,4-oxa­diazole ligands mutually trans, as the Pt atom lies on an inversion center. The 4-chloro­benzaldehyde mol­ecules are statistically disordered about an inversion centre with equal occupancies for the two positions. The PtII complex forms a three-dimensional structure through C—H⋯Cl and weaker C—H⋯O inter­actions with the 4-chloro­benzaldehyde mol­ecule.

Zinc(ii)-mediated generation of 5-amino substituted 2,3-dihydro-1,2,4-oxadiazoles and their further ZnII-catalyzed and O2-involving transformations

“…62 The X-ray data for these four species represent the second example of structurally characterized metal-free DHODs and the first example of crystallographically characterized 5-aminosubstituted DHOD. Only one work reported metal-free structures of DHODs, 61 whereas more examples of structurally characterized metal-bound DHODs were previously reported and these structures include DHOD complexes of Pd II , 16 Pt II , 14,15,[19][20][21][26][27][28][63][64][65] Pt IV , 19,21 and closo-decaborate clusters bearing the DHOD moiety. 46,66 Zn II -Catalyzed and O 2 -involving transformations of DHODs…”

“…2 ) giving complexed DHODs. [14][15][16]27,28 All these metal-involved reactions have some disadvantages with regard to the preparation of DHODs. In particular, the cycloaddition requires a stoichiometric amount of a metal source (viz.…”