Smart
soft materials are envisioned to be the building blocks of
the next generation of advanced devices and digitally augmented technologies.
In this context, liquid crystals (LCs) owing to their responsive and
adaptive attributes could serve as promising smart soft materials.
LCs played a critical role in revolutionizing the information display
industry in the 20th century. However, in the turn of the 21st century,
numerous beyond-display applications of LCs have been demonstrated,
which elegantly exploit their controllable stimuli-responsive and
adaptive characteristics. For these applications, new LC materials
have been rationally designed and developed. In this Review, we present
the recent developments in light driven chiral LCs, i.e., cholesteric
and blue phases, LC based smart windows that control the entrance
of heat and light from outdoor to the interior of buildings and built
environments depending on the weather conditions, LC elastomers for
bioinspired, biological, and actuator applications, LC based biosensors
for detection of proteins, nucleic acids, and viruses, LC based porous
membranes for the separation of ions, molecules, and microbes, living
LCs, and LCs under macro- and nanoscopic confinement. The Review concludes
with a summary and perspectives on the challenges and opportunities
for LCs as smart soft materials. This Review is anticipated to stimulate
eclectic ideas toward the implementation of the nature’s delicate
phase of matter in future generations of smart and augmented devices
and beyond.