Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV)

Abstract

In the title compound, (C12H24N)[Sn(CH3)3(C6H6O3P)2], the SnMe3 residues are axially coordinated by two monodentate [PhPO3H]− anions, leading to a trigonal–bipyramidal geometry for the SnIV atom. The two [SnMe3(PhPO3H)2]− anions in the unit cell are associated into infinite chains along the a axis by O—H⋯O hydrogen bonds involving the hy­droxy group of the hydrogen phenyl­phospho­nate ion. The chains inter­act with one another via O—H⋯O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclo­hexyl­ammonium ion through N—H⋯O hydrogen bonds, forming a three-dimensional network.

Poly[tetrabutyltetrakis(μ2-hydrogen phenylphosphonato)ditin(IV)]

“…This fragment is located on a inversion center. Each Sn1 atom is linked to two others dimers based on Sn2 atoms, via other bridging hydrogenophenylphosphonates (P2, P3, P4), The hydrogen bonds lead to almost equal P-O bond distances [P1-O1: 1.513 (3) Å, P1-O2: 1.516 (3) Å, different of the P-OH bond: P1-O3: 1.563 (3) Å], as reported for dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)-stannate(IV) (Diop et al, 2011). The geometry around the P atom is a distorted tetrahedron [O1-P1-O2:…”

Triorganotin Phosphonates Polymeric Chains - Synthesis, Infrared, Mossbauer and Single Crystal Characterization:the First Organotin(iv) Ph2- Bridged.

“…-Molecular structure of 1showing the trigonal bipyramidal polyhedron at tin atoms. Ellipsoids are drawn at 50% probability.The Sn-C distances are in the range of those found in tbp SnMe 3 moieties(Diop et al, 2013a(Diop et al, , 2012b(Diop et al, , 2011a. The Sn1-O4 bond of 2.416 (2) Å is longer, weaker than the Sn1-O1 one of 2.1313(19) Å: these values are in a typical range of Sn-O phosphonate (Diop et al, 2013a, 2012a, 2012b) and Sn-O water (Diop et al, 2015), respectively.…”

“…In some of these structures, the hydrogenphosphonate anion behaves as multidirectional synthons. Contributing to widen phosphonate family compounds, the Dakar group has already reported the spectroscopic (Infrared, Mössbauer and NMR) studies of some RPO 3 (SnPh 3 ) 2 (R = H or CH 3 ) (Diop et al, 1999), the crystal characterization of dibutylammonium bis(hydrogen methylphosphonato-κO)triphenylstannate(IV) (Diop et al, 2012a) as well as numerous phenylphosphonato triphenyltin(IV) crystalline structures which, through hydrogen bonding interactions, exhibit various structures that give rise to supramolecular diverse topologies (Diop et al, 2013a(Diop et al, , 2012b(Diop et al, , 2011a(Diop et al, , 2011b. To the best of our knowledge (CSD version 5.40), very few, only three tin(IV) methylphosphonate and five tin(IV) hydrogenphosphonate containing crystalline compoundsare known (Diop et al, 2012a;Ribot et al, 2001;Adair et al, 1998;Chandrasekharet al, 2003Chandrasekharet al, , 2005Mairychova et al, 2014 (Mairychova et al, 2014) or an hexameric cage structure in a double O-capped cluster with tri-O-coordinating ligands (Chandrasekharet al, 2003(Chandrasekharet al, , 2005.…”

Supramolecular architecture in crystalline Bu2NH2(PhPO3H)2SnMe3

“…Our group has published some articles dealing with SnMe 3 and SnPh 3 residues containing derivatives (Diop et al , 2002(Diop et al , , 2011Diallo et al , 2009 ). In this work, we initiated the study of the interactions between Bu 2 NH 2 PhPO 3 H and SnMe 3 Cl which gave the title compound.…”