Angewandte Chemie
 2016
DOI: 10.1002/ange.201608508
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Die erste organokatalytische Cope‐Umlagerung

Konrad Gebauer
1
,
Christoph Schneider
2

Abstract: Auf dem Konzept der Iminiumionenkatalyse beruht die erste breit anwendbare organokatalytische Cope‐Umlagerung von 1,5‐Hexadien‐2‐carboxaldehyden. Ein Diazepankatalysator zeigt optimale katalytische Aktivität und konnte darüber hinaus chiral modifiziert werden.

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