The composites (x)CoFe2O4‐(1‐x)Ba0.8Sr0.2TiO3 were prepared by solid state reaction method using microwave double‐step sintering. Ba0.8Sr0.2TiO3 crystalized to tetragonal crystal symmetry with P4mm space group and, CoFe2O4 crystalized to cubic crystal symmetry with F
d3̅𝑚
space group. Electron microscopy techniques were used to understand the microstructure, elemental composition, and morphology of the composites. The dielectric properties were measured in the 1Hz‐1MHz frequency range and, 400C‐4000C temperature range. Composite with × = 0.1 (ε’∽170, tan δ=0.08 at 1kHz) and 0.2 (ε’∽390, tan δ=0.07 at 1 kHz) have better dielectric properties than the parent Ba0.8Sr0.2TiO3 ferroelectric (ε’∽125, tan δ=0.16 at 1kHz) and CoFe2O4 ferrimagnetic phases (ε’∽375, tan δ=0.72 at 1kHz), respectively. Composite with 10% cobalt ferrite has the highest saturation polarization (2.1 μC/cm2), highest remanent polarization (0.9 μC/cm2), and coercive field (23.9 kV/cm) compared to ferroelectric phase followed by × = 0.2 composite (P
S
= 1.6 μC/cm2, P
r
= 0.8 μC/cm2 & E
C
= 19.2 kV/cm). Composite with × = 0.2 show the highest magnetic coercive field of 1.96 kOe. Hence, this article advocates that 20% ferrite in the composites is the optimized composition for multiferroic applications. The present study will help explore piezoelectric, magnetostrictive, and magnetoelectric properties of (x)CoFe2O4‐(1‐x)Ba0.8Sr0.2TiO3 for the technological application.This article is protected by copyright. All rights reserved.