Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.005 Å; R factor = 0.030; wR factor = 0.067; data-to-parameter ratio = 21.9.The asymmetric unit of the title compound, (C 6 H 7 ClN) 4 -[SnCl 6 ]Cl 2 , comprises two 4-chloroanilinium cations, half of an [SnCl 6 ] 2À anion and a Cl À anion. The Sn IV atom, located on a special position on a twofold rotation axis, exhibits an octahedral environment. In the crystal, molecules are linked by N-HÁ Á ÁCl hydrogen bonds between the 4-chloroanilinium cations, [SnCl 6 ] 2À anions and Cl À anions.
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